Skip to main content
Log in

Electroluminescent copper-containing polymers based on copper(I) norbornene-substituted complexes

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

New copper(I) complexes with norbornene-substituted benzimidazole ligands were synthesized. On the base of the obtained compounds carbon-chain copper-containing copolymers possessing photo- and electroluminescent properties were obtained by the metathesis polymerization method. Polymeric emitters show electroluminescence of yellow and orange colors with a maximum brightness as high as 629 cd/m2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Dumur, F., Org. Electr., 2015, vol. 21, p. 27. doi 10.1016/j.orgel.2015.02.026

    Article  CAS  Google Scholar 

  2. Volz, D., Baumann, T., Flugge, H., Mydlak, M., Grab, T., Bachle, M., Barner-Kowollik, C., and Brase, S., J. Mater. Chem., 2012, vol. 22, p. 20786. doi 10.1039/C2JM33291D

    Article  CAS  Google Scholar 

  3. Barinova, Yu.P., Ilicheva, A.I., Bochkarev, L.N., Ilichev, V.A., and Kurskii, Yu A., Russ. J. Gen. Chem., 2013, vol. 83, no. 1, p. 72. doi 10.1134/S107036321301012X

    Article  CAS  Google Scholar 

  4. Il’icheva, A.I., Barinova, Yu.P., Bochkarev, L.N., and Il’ichev, V.A., Russ. J. Appl. Chem., 2012, vol. 85, no. 11, p. 1711. doi 10.1134/S1070427212110146

    Article  Google Scholar 

  5. Si, Z, Li, J, Li, B., Liu, S., and Li, W., J. Lumin., 2009, vol. 129, p. 181. doi 10.1016/j.jlumiH.2008.09.014

    Article  CAS  Google Scholar 

  6. Min, J., Zhang, Q., Sun, W., Cheng, Y, and Wang, L., Dalton Trans., 2011, vol. 40, p. 686. doi 10.1039/c0dt01031f

    Article  CAS  Google Scholar 

  7. Sanz, A. and Mendicuti, F., Polymer, 2002, vol. 43, p. 6123. doi 10.1016/S0032-3861(02)00584–0

    Article  CAS  Google Scholar 

  8. Hoyle, C.E., Nemzek, T.L., Mar, A., and Guillet, J.E., Macromolecules, 1978, vol. 11, p. 429. doi 10.1021/ma60062a029

    Article  CAS  Google Scholar 

  9. Förster, T., Discuss. Faraday Soc., 1959, vol. 27, p. 7. doi 10.1039/DF9592700007

    Article  Google Scholar 

  10. Tsuboyama, A., Kuge, K., Furugori, M., Okada, S., Hoshino, M, and Ueno, K., Inorg. Chem., 2007, vol. 46, no. 6, p. 1992. doi 10.1021/ic0608086

    Article  CAS  Google Scholar 

  11. Ilicheva, A.I., Bochkarev, L.N., Ilichev, V.A., and Semchikov, Yu.D., Russ. J. Gen. Chem., 2015, vol. 85, no. 5, p. 1140. doi 10.1134/S1070363215050230

    Article  CAS  Google Scholar 

  12. Ye, Q., Gao, T., Wan, F., Yu, B., Pei, X., Zhou, F., and Xue, Q., J. Mater. Chem., 2012, vol. 22, p. 13123. doi 10.1039/C2JM31527K

    Article  CAS  Google Scholar 

  13. Chen, T.-R., Mater. Lett., 2005, vol. 59, p. 1050. doi 10.1016/j.matlet.2004.12.002

    Article  CAS  Google Scholar 

  14. Liaw, D.-J. and Tsai, C.-H., Polymer, 2000, vol. 41, p. 2773. doi 10.1016/S0032-3861(99)00491–7

    Article  CAS  Google Scholar 

  15. Kubas, G.J., Inorg. Synth., 1979, vol. 19, p. 90. doi 9780470132500.ch18

    CAS  Google Scholar 

  16. Scholl, M., Ding, S, Lee, C.W., and Grubbs, R.H., Org. Lett., 1999, vol. 1, p. 953. doi 10.1021/ol990909q

    Article  CAS  Google Scholar 

  17. Love, J.A., Morgan, J.P., Trnka, T.M., and Grubbs, R.H., Angew. Chem. Int. Ed., 2002, vol. 41, p. 4035. doi 1521-3773(20021104)41:21〈4035::AIDANIE4035〉3.0.CO;2-I

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to L. N. Bochkarev.

Additional information

Original Russian Text © A.I. Ilicheva, L.N. Bochkarev, V.A. Ilichev, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 6, pp. 964–971.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ilicheva, A.I., Bochkarev, L.N. & Ilichev, V.A. Electroluminescent copper-containing polymers based on copper(I) norbornene-substituted complexes. Russ J Gen Chem 87, 1184–1191 (2017). https://doi.org/10.1134/S1070363217060135

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363217060135

Keywords

Navigation