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The effect of chemical modification of the macrocycle on the complex formation between porphyrins and metal salts in organic solvents

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Abstract

The complex formation of β-octaethylporphyrin, β-octaethyl-meso-monophenylporphyrin, β-octaethyl-meso-tetraphenylporphyrin, meso-diphenylporphyrin, meso-triphenylporphyrin, and meso-tetraphenylporphyrin with Zn(II), Cu(II), Co(II), and Mn(II) acetates and chlorides in dimethylformamide, dimethylsulfoxide, pyridine, acetic acid, and a chloroform–methanol 1 : 1 mixture has been studied by means of spectrophotometry. The observed regulations are in line with the concept of chemical reactivity of the N–H bonds in porphyrins of different complexity.

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Authors and Affiliations

  1. Krestov Institute of Solutions Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    O. V. Maltceva & N. Zh. Mamardashvili

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  1. O. V. Maltceva
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  2. N. Zh. Mamardashvili
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Correspondence to O. V. Maltceva.

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Original Russian Text © O.V. Maltceva, N.Zh. Mamardashvili, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 6, pp. 955–963.

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Maltceva, O.V., Mamardashvili, N.Z. The effect of chemical modification of the macrocycle on the complex formation between porphyrins and metal salts in organic solvents. Russ J Gen Chem 87, 1175–1183 (2017). https://doi.org/10.1134/S1070363217060123

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  • DOI: https://doi.org/10.1134/S1070363217060123

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