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Selective monoallylation of β-cyclodextrin

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Abstract

Reaction of β-cyclodextrin with allyl bromide in dimethyl sulfoxide affords 2-О-allyl-β-cyclodextrin, while in dimethylformamide 6-О-allyl-β-cyclodextrin is formed. Optimal conditions of the reaction were found allowing to obtain the target products in quantitative yield.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    V. V. Novokshonov

  2. Irkutsk National Research Technical University, ul. Lermontova 83, Irkutsk, 664074, Russia

    Nguen Chyong Hoi & N. S. Shaglaeva

Authors
  1. V. V. Novokshonov
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  2. Nguen Chyong Hoi
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  3. N. S. Shaglaeva
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Corresponding author

Correspondence to N. S. Shaglaeva.

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Original Russian Text © V.V. Novokshonov, Nguen Chyong Hoi, N.S. Shaglaeva, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 6, pp. 951–954.

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Novokshonov, V.V., Hoi, N.C. & Shaglaeva, N.S. Selective monoallylation of β-cyclodextrin. Russ J Gen Chem 87, 1172–1174 (2017). https://doi.org/10.1134/S1070363217060111

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  • DOI: https://doi.org/10.1134/S1070363217060111

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