Skip to main content
SpringerLink
Log in

Interaction of ferrocene with styrene and methyl methacrylates in the media of different polarity

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

The interaction of ferrocene with styrene and methyl methacrylate in media of different polarity (hexane, tetrachloromethane, and ethanol) has been studied by means of UV spectroscopy using the isomolar series method. For both monomers, intermediate complexes are formed, the medium polarity significantly affecting the complexes formation. Ferrocene acts differently in the interaction with styrene (being the electron acceptor) and methyl methacrylate (being the electron donor). It has been discovered that only in the case of ethanol a charge-transfer complex between ferrocene and styrene is formed. Possible structures of the intermediate complexes have been suggested.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Shchepalov, A.A. and Grishin, D.F., Polymer Sci. (A), 2008, vol. 50, no. 4, p. 382. doi 10.1134/S0965545X08040044

    Google Scholar 

  2. Puzin, Yu.I., Yumagulova, R.Kh., and Kraikin, V.A., Eur. Polym. J., 2001, vol. 37, no. 9, p. 1801. doi 10.1016/S0014-3057(01)00038-6

    Article  CAS  Google Scholar 

  3. Puzin, Yu.I., Leplyanin, G.V., Tolstikov, G.A., and Shaul’skii, Yu.M., Eur. Polym. J., 1988, vol. 24, no. 6, p. 579.

    Article  CAS  Google Scholar 

  4. Kraikin, V.A., Ionova, I.A., Puzin, Yu.I., Yumagulova, R.Kh., and Monakov, Yu.B., Polymer Sci. (A), 2000, vol. 42, no. 9, p. 1042.

    Google Scholar 

  5. Islamova, R.M., Nasretdinova, R.N., Puzin, Yu.I., Semeikin, A.S., Koifman, O.I., and Monakov, Yu.B., Izv. Vuzov, Ser. Khim. Khim. Tekhnol., 2005, vol. 48, no. 12, p. 54.

    CAS  Google Scholar 

  6. Kolesov, S.V., Yumagulova, R.Kh., Prokudina, E.M., Puzin, Yu.I., Kuznetsov, S.I., and Ionova, I.A., Polymer Sci. (B), 2003, vol. 45, nos. 1–2, p. 13.

    Google Scholar 

  7. Puzin, Yu.I., Prokudina, E.M., Yumagulova, R.Kh., Muslukhov, R.R., and Kolesov, S.V., Doklady Phys. Chem., 2002, vol. 386, nos. 1–3, p. 211. doi 10.1023/A:1020343820445

    Article  CAS  Google Scholar 

  8. Kolesov, S.V., Sigaeva, N.N., Gazeeva, D.R., Ermolaev, N.L., and Yumagulova, R.Kh., Vestn. Bash. Univ., 2009, vol. 14, no. 3, p. 746.

    Google Scholar 

  9. Puzin, Yu.I. and Gafurov, M.A., Russ. J. Gen. Chem., 2015, vol. 85, no. 10, p. 2334. doi 10.1134/S1070363215100187

    Article  CAS  Google Scholar 

  10. Frizen, A.K., Cand. Sci. (Chem.) Dissertation, Ufa, 2007.

    Google Scholar 

  11. Kuramoto, N., Ogino, H., Kido, J., and Nagai, K., J. Polymer Sci. (A), 1995, vol. 33, no. 6, p. 967.

    CAS  Google Scholar 

  12. Prokudina, E.M., Cand. Sci. (Chem.) Dissertation, Ufa, 2004.

    Google Scholar 

  13. Shlefer, H.L., Komplexierung in Lösungen, Berlin: Springer, 1961.

    Book  Google Scholar 

  14. Rabek, J.F., Experimental Methods in Polymer Chemistry, Chichester: Wiley, 1980

    Google Scholar 

  15. Laidler, K.J., Chemical Kinetics, New York: McGraw-Hill, 1965.

    Google Scholar 

  16. Nesmeyanov, A.N., Khimiya ferrotsena (Chemistry of Ferrocene), Moscow: Nauka, 1969.

    Google Scholar 

  17. Bogomolova, T.B., Gantmakher, A.R., and Lyudvig, E.B., Vysokomol. Soedin. (A), 1972, vol. 14, no. 10, p. 2210.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ufa State Oil Technological University, ul. Kosmonavtov 1, Ufa, 450062, Russia

    Yu. I. Puzin

  2. Ufa Institute of Chemistry, Russian Academy of Sciences, Ufa, Russia

    S. I. Kuznetsov

  3. Togliatti State University, Togliatti, Russia

    A. A. Golovanov

Authors
  1. Yu. I. Puzin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. I. Kuznetsov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. A. Golovanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. I. Puzin.

Additional information

Original Russian Text © Yu.I. Puzin, S.I. Kuznetsov, A.A. Golovanov, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 5, pp. 838–843.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Puzin, Y.I., Kuznetsov, S.I. & Golovanov, A.A. Interaction of ferrocene with styrene and methyl methacrylates in the media of different polarity. Russ J Gen Chem 87, 1026–1030 (2017). https://doi.org/10.1134/S107036321705022X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107036321705022X

Keywords

Search

Navigation