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Imines derived from 4-methyl-4-diphenylphosphorylpentan-2-one and potassium salts of aminocarboxylic acids

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Abstract

An effective procedure for the preparation of imines based on 4-methyl-4-diphenylphosphorylpentan-2-one, aminoacetic, aminopropionic, and aminobutyric acids with yields of 90–95% was developed. Reaction of dimephosphone (4-methyl-4-dimethoxyphosphorilpentan-2-one) with potassium salts of these amino acids led to methylation of the carboxy group of the amino acid to form potassium salt of 2-methyl-4-oxopentylphosphonic acid methyl ester.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088, Russia

    M. N. Dimukhametov, V. F. Mironov & D. A. Tatarinov

  2. Kazan (Volga Region) Federal University, Kazan, Tatarstan, Russia

    V. F. Mironov & D. A. Tatarinov

Authors
  1. M. N. Dimukhametov
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  2. V. F. Mironov
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  3. D. A. Tatarinov
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Correspondence to V. F. Mironov.

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Original Russian Text © M.N. Dimukhametov, V.F. Mironov, D.A. Tatarinov, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 4, pp. 686–688.

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Dimukhametov, M.N., Mironov, V.F. & Tatarinov, D.A. Imines derived from 4-methyl-4-diphenylphosphorylpentan-2-one and potassium salts of aminocarboxylic acids. Russ J Gen Chem 87, 882–884 (2017). https://doi.org/10.1134/S1070363217040363

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  • DOI: https://doi.org/10.1134/S1070363217040363

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