Abstract
The protolytic equilibria in solutions of complexones, derivatives of ethylenediamine-N,N,N',N'-tetraacetic acid, were studied. The standard thermodynamic characteristics of step dissociation of these diamine complexones were calculated and interrelated with the structural features of these compounds.
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Vasil’ev, V.P., Lymar, V.P., and Lytkin, A.I., Zh. Neorg. Khim., 1977, vol. 22, no. 9, pp. 2511–2517.
Vasil’ev, V.P., Lymar, V.P., and Lytkin, A.I., Zh. Neorg. Khim., 1977, vol. 22, no. 10, pp. 2652–2656.
Vasil’ev, V.P., Kochergina, L.A., and Orlova, T.D., Zh. Obshch. Khim., 1978, vol. 48, no. 12, p. 2770.
Vasil’ev, V.P., Kochergina, L.A., and Orlova, T.D., Zh. Obshch. Khim., 1979, vol. 49, no. 7, pp. 1649–1653.
Vasil’ev, V.P., Kochergina, L.A., and Orlova, T.D., Zh. Obshch. Khim., 1976, vol. 46, no. 10, pp. 2192–2195.
Vasil’ev, V.P., Kochergina, L.A., and Yastrebova, T.D., Zh. Obshch. Khim., 1973, vol. 43, no. 5. pp. 975–980.
Vasil’ev, V.P., Kochergina, L.A., and Yastrebova, T.D., Zh. Obshch. Khim., 1974, vol. 44, no. 6, pp. 1371–1375.
Gridchin, S.N. and Kochergina, L.A., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2004, vol. 47, no. 7, pp. 36–38.
Gridchin, S.N., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2006, vol. 49, no. 9, pp. 14–17.
Gridchin, S.N., Russ. J. Inorg. Chem., 2008, vol. 53, no. 10, p. 1672. doi 10.1134/S0036023608100252
Gridchin, S.N., Russ. J. Gen. Chem., 2010, vol. 80, no. 3, p. 395. doi 10.1134/S1070363210030047
Gridchin, S.N., Russ. J. Phys. Chem. A, 2009, vol. 83, no. 1, p. 41. doi 10.1134/S0036024409010099
Vasil’ev, V.P., Kochergina, L.A., Ivanova, T.V., Grosheva, S.G., and Kadykova, I.V., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1991, vol. 34, no. 8, pp. 54–59.
Gridchin, S.N., Nikol’skii, V.M., and Tolkacheva, L.N., Russ. J. Phys. Chem. A, 2014, vol. 88, no. 10, p. 1813. doi 10.1134/S0036024414100148.
Gridchin, S.N., Nikol’skii, V.M., and Tolkacheva, L.N., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2015, vol. 58, no. 2, pp. 11–13.
Vasil’ev, V.P., Kozlovskii, E.V., and Ledenkov, S.F., in Teoreticheskie metody opisaniya svoistv rastvorov (Theoretical Methods for Describing the Properties of Solutions), Ivanovo: Ivanov. Khim.-Tekhnol. Inst., 1987, pp. 81–86.
Gridchin, S.N., Kochergina, L.A., Vasil’ev, V.P., and Pyreu, D.F., Russ. J. Inorg. Chem., 2002, vol. 47, no. 7, p. 1017.
Vasil’ev, V.P., Gridchin, S.N., Kochergina, L.A., and Chernikov, V.V., Russ. J. Phys. Chem., 1998, vol. 72, no. 5, p. 763.
Gridchin, S.N., Russ. J. Phys. Chem., 2005, vol. 79, no. 11, p. 1870.
Gridchin, S.N., Russ. J. Phys. Chem. A, 2008, vol. 82, no. 1, p. 41. doi 10.1134/S0036024408010044
Gridchin, S.N. and Nikol’skii, V.M., Russ. J. Phys. Chem. A, 2014, vol. 88, no. 4, p. 573. doi 10.1134/S0036024414040098
Gridchin, S.N. and Pyreu, D.F., Russ. J. Phys. Chem. A, 2011, vol. 85, no. 4, p. 706. doi 10.1134/S0036024411040108
Gridchin, S.N., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2005, vol. 48, no. 12, pp. 51–53.
Vasil’ev, V.P., Termodinamicheskie svoistva rastvorov elektrolitov (Thermodynamic Properties of Solutions of Electrolytes), Moscow Vysshaya Shkola, 1982.
Gridchin, S.N. and Bazanov, M.I., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2008, vol. 51, no. 6, pp. 23–26.
Vasil’ev, V.P., Kochergina, L.A., and Garavin, V.Yu., Zh. Obshch. Khim., 1992, vol. 62, no. 1, pp. 213–218.
Gridchin, S.N., Shekhanov, R.F., and Pyreu, D.F., Russ. J. Phys. Chem., 2015, vol. 89, no. 2, p. 341. doi 10.1134/S0036024415020120
Vasil’ev, V.P., Kochergina, L.A., Garavin, V.Yu., and Grudochkin, A.V., in Teoreticheskie metody opisaniya svoistv rastvorov (Theoretical Methods for Describing the Properties of Solutions), Ivanovo: Ivanov. Khim.- Tekhnol. Inst., 1987, pp. 87–92.
Gorboletova, G.G., Gridchin, S.N., and Sazonova, E.S., Russ. J. Phys. Chem., 2005, vol. 79, no. 8, p. 1222.
Gridchin, S.N., Gorboletova, G.G., and Pyreu, D.F., J. Therm. Anal. Cal., 2007, vol. 90, no. 2, pp. 607–609.
Vasil’ev, V.P., Kochergina, L.A., and Krutova, O.N., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2003, vol. 46, no. 6, pp. 69–72.
Gridchin, S.N. and Pyreu, D.F., Russ. J. Gen. Chem., 2007, vol. 77, no. 6, p. 1037. doi 10.1134/S107036320706014X
Gridchin, S.N., Russ. J. Gen. Chem., 2015, vol. 85, no. 4, p. 810. doi 10.1134/S1070363215040064
Vasil’ev, V.P., Kochergina, L.A., Iven’kova, S.G., Sasakina, S.Yu., and Tsirul’nikova, N.V., Zh. Obshch. Khim., 1986, vol. 56, no. 6, pp. 1366–1373.
Lytkin, A.I., Chernyavskaya, N.V., Rumyantseva, I.A., Orlova, T.D., and Nikol’skii, V.M., Russ. J. Phys. Chem., 2006, vol. 80, no. 4, p. 491.
Vasil’ev, V.P., Kochergina, L.A., Orlova, T.D., and Samoshina, T.D., Zh. Obshch. Khim., 1981, vol. 51, no. 2, pp. 292–299.
Vasil’ev, V.P., Kochergina, L.A., and Chernikov, V.V., Kompleksony i kompleksonaty (Complexones and Complexonates), Kalinin: Kalininsk. Gos. Univ., 1988, pp. 80–84.
Vasil’ev, V.P., Kochergina, L.A., Iven’kova, S.G., and Kuturov, M.V., Zh. Obshch. Khim., 1982, vol. 52, no. 7, pp. 1657–1663.
Gridchin, S.N., Romodanovskii, P.A., and Pyreu, D.F., Russ. J. Phys. Chem., 2009, vol. 83, no. 1, p. 138. doi 10.1134/S0036024409010270
Advani, A.T., Irving, H.M.N.H., and Pettit, L.D., J. Chem. Soc. A, 1970, pp. 2649–2651.
Novak, V. and Lukansky, J., Chem. Zvesti, 1978, vol. 32, p. 32.
Novak, V. and Svicekova, M., Chem. Zvesti, 1981, vol. 35, p. 481.
Charlier, L., Merciny, E., and Fuger, J., Anal. Chim. Acta, 1985, vol. 178, p. 299–306.
Gridchin, S.N. and Bazanov, M.I., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2007, vol. 50, no. 2, pp. 85–88.
Novomesky, P. and Balgavy, P., Farm. Obz., 1981, vol. 50, no. 8, p. 397–406.
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Original Russian Text © S.N. Gridchin, 2015, published in Rossiiskii Khimicheskii Zhurnal, 2015, Vol. 59, Nos. 1–2, pp. 109–115.
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Gridchin, S.N. Thermochemical studies of the acid-base interactions in solutions of complexones, derivatives of ethylenediamine-N,N,N',N'-tetraacetic acid. Russ J Gen Chem 87, 655–662 (2017). https://doi.org/10.1134/S1070363217030446
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DOI: https://doi.org/10.1134/S1070363217030446