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Calorimetric study of the molecular complex formation of glycyl–glycyl–glycine with 18-crown-6 in aqueous organic solvents

  • Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
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Abstract

The influence of water–ethanol (H2O–EtOH), water–acetone (H2O–MeAc) and waterdimethylsulfoxide (H2O–DMSO) solvents on the reaction of the molecular complex formation between ether 18-crown-6 (18C6) and small peptide glycyl–glycyl–glycine (3Gly) has been studied at T = 298.15 K. The thermodynamic parameters for the reaction (log K, Δr G, Δr H, Δr S) were obtained from calorimetric titration experiments carried out by means of the calorimetric system TAM III (TA Instruments, USA). The thermodynamics of the [3Gly18C6] molecular complex formation is discussed in comparison with thermodynamic parameters of complex formation between 18C6 and amino acids in mixed solvents using the sоlvation-thermodynamic approach.

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology (ISUCT), pr. Sheremetevskii 7, Ivanovo, 153000, Russia

    T. R. Usacheva, L. Pham Thi & V. A. Sharnin

  2. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153040, Russia

    V. A. Sharnin

  3. Institute for Tropical Technology, Vietnam Academy of Sciences and Technology, Hoang Quoc Viet str. 18, Hanoi, Vietnam

    L. Pham Thi

Authors
  1. T. R. Usacheva
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  2. L. Pham Thi
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  3. V. A. Sharnin
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Correspondence to T. R. Usacheva.

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Original Russian Text © T.R. Usacheva, L. Pham Thi, V.A. Sharnin, 2015, published in Rossiiskii Khimicheskii Zhurnal, 2015, Vol. 59, Nos. 1–2, pp. 21–29.

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Usacheva, T.R., Pham Thi, L. & Sharnin, V.A. Calorimetric study of the molecular complex formation of glycyl–glycyl–glycine with 18-crown-6 in aqueous organic solvents. Russ J Gen Chem 87, 591–599 (2017). https://doi.org/10.1134/S1070363217030355

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  • DOI: https://doi.org/10.1134/S1070363217030355

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