Russian Journal of General Chemistry

, Volume 87, Issue 1, pp 86–91 | Cite as

Self-assembling in the systems МХ2–2-(7-bromo-2-oxo-5-phenyl-2,3-dihydro-1Н-1,4-benzdiazepin-1-yl)acetohydrazide–salicyl aldehyde (М = Сo, Ni, Zn; X = Cl, CH3COO)

  • A. V. Pulya
  • I. I. Seifullina
  • L. S. Skorokhod
  • V. G. Vlasenko
  • A. L. Trigub
  • Ya. V. Zubavichus
  • S. I. Levchenkov
Article

Abstract

By self-assembling in the systems MX2–2-(7-bromo-2-oxo-5-phenyl-2,3-dehydro-1Н-1,4-benzdiazepin-1-yl)acetohydrazide (Hydr)–salicyl aldehyde (HSal) (М = Co, Ni, Zn; X = Cl, CH3COO) the complexes of composition [Co(HydrSal)2], [Ni(HydrSal)2], [Zn(HydrHSal)Cl2], [Zn(HydrSal)(CH3COO)(H2O)] have been synthesized. The local atomic structure of the coordination unit was determined by the method of X-ray absorption spectroscopy. Thermal stability, electroconductivity, and magnetic susceptibility of the complexes have been studied.

Keywords

coordination compounds cobalt(II) nickel(II) zinc(II) 2-(7-bromo-2-oxo-5-phenyl-2,3-dehydro-1Н-1,4-benzdiazepin-1-yl)acetohydrazide salicylaldehyde 

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References

  1. 1.
    Pulya, A.V., Seifullinna, I.I., Skorokhod, L.S., Efimov, N.N., Ugolkova, E.A., and Minin, V.V., Russ. J. Inorg. Chem., 2015, vol. 60, no. 1, p. 51. doi 10.1134/S0036023615010106CrossRefGoogle Scholar
  2. 2.
    Pulya, A.V., Seifullinna, I.I., Skorokhod, L.S., Vlasenko, V.G., Levchenkov, S.I., and Pavlovskii, V.I., Russ. J. Gen. Chem., 2015, vol. 85, no. 1, p. 97. doi 10.1134/S1070363211501017XCrossRefGoogle Scholar
  3. 3.
    Pulya, A.V., Seifullinna, I.I., Skorokhod, L.S., Efimov, N.N., Ugolkova, E.A., and Minin, V.V., Russ. J. Inorg. Chem., 2016, vol. 61, no. 1, p. 38. doi 10.1134/S0036023616010204CrossRefGoogle Scholar
  4. 4.
    Pulya, A.V., Seifullinna, I.I., Skorokhod, L.S., Vlasenko, V.G., Zubavichus, Ya.V., and Levchenkov, S.I., Russ. J. Gen. Chem., 2015, vol. 85, no. 5, p. 1125. doi 10.1134/S1070363215050205CrossRefGoogle Scholar
  5. 5.
    Nakamoto, K., Infrared Spectra of Inorganic and Coordination Compounds, New York Wiley, 1963.Google Scholar
  6. 6.
    Rakitin, Yu.V. and Kalinnikov, V.T., Sovremennaya magnetokhimiya (Modern Magnetochemistry), St. Petersburg Nauka, 1994.Google Scholar
  7. 7.
    Geary, W.J., Coord. Chem. Rev., 1971, vol. 7, p. 81. doi 10.1016/S0010-8545(00)80009-0CrossRefGoogle Scholar
  8. 8.
    Chernyshov, A.A., Veligzhanin, A.A., and Zubavichus, Ya.V., Nucl. Instr. Meth. Phys. Res. (A), 2009, vol. 603, p. 95. doi 10.1016/j.nima.2008.12.167CrossRefGoogle Scholar
  9. 9.
    Kochubei, D.I., Baranov, Yu.A., Zamaraev, K.I., Vedrinskii, R.V., Kraizman, V.L., Kulipanov, G.N., Mazalov, L.N., Skrinskii, A.N., Fedorov, V.I., Khel’mer, B.Yu., and Shuvaev, A.T., Rentgeno-spektral’nyi metod izucheniya struktury amorfnykh tel: EXAFS-spektroskopiya (X-Ray Spectral Method for Studying the Structure of Amorphous Solids: EXAFSSpectroscopy), Novosibirsk Nauka, Sib. Otd., 1988.Google Scholar
  10. 10.
    Newville, M., J. Synchrotron Rad., 2001, vol. 8, p. 96. doi 10.1107/S0909049500016290CrossRefGoogle Scholar
  11. 11.
    Zabinski, S.I., Rehr, J.J., Ankudinov, A., and Alber, R.C., Phys. Rev., 1995, vol. 52, p. 2995. doi 10.1103/PhysRevB.52.2995CrossRefGoogle Scholar
  12. 12.
    Klyuchnikov, N.G., Rukovodstvo po neorganicheskomu sintezu (Guide for Inorganic Synthesis), Moscow: Khimiya, 1965, p. 104.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • A. V. Pulya
    • 1
  • I. I. Seifullina
    • 1
  • L. S. Skorokhod
    • 1
  • V. G. Vlasenko
    • 2
  • A. L. Trigub
    • 3
  • Ya. V. Zubavichus
    • 3
  • S. I. Levchenkov
    • 4
  1. 1.I.I. Mechnikov Odessa National UniversityOdessaUkraine
  2. 2.Research Institute of PhysicsSouthern Federal UniversityRostov-on-DonRussia
  3. 3.Russian Scientific Center “Kurchatov Institute”MoscowRussia
  4. 4.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia

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