Russian Journal of General Chemistry

, Volume 87, Issue 1, pp 66–75

A new ligand system containing sulfanilamide and quinazolinone fragments: Synthesis, structure, and properties

  • L. D. Popov
  • S. A. Borodkin
  • A. A. Tsaturyan
  • Yu. P. Tupolova
  • S. I. Levchenkov
  • V. V. Minin
  • A. S. Burlov
  • Yu. V. Revinskii
  • I. N. Shcherbakov
  • E. A. Raspopova
Article

DOI: 10.1134/S1070363217010121

Cite this article as:
Popov, L.D., Borodkin, S.A., Tsaturyan, A.A. et al. Russ J Gen Chem (2017) 87: 66. doi:10.1134/S1070363217010121
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Abstract

A new Schiff base ligand, 4-methyl-N-{2-[(2-methyl-4-oxo-3,4-dihydroquinazolin-3-yl)iminomethyl]-phenyl}benzenesulfonamide (L), and its complexes with transition metals [Cd(L)2], [Zn(L)2], and [CuLOAc] have been synthesized. The structure and electronic properties of the ligand have been studied by quantum chemical methods, and its zinc and cadmium complexes have been found to exhibit luminescence properties.

Keywords

metal complexes Schiff base NMR spectroscopy quantum chemical calculations electronic spectroscopy luminescence spectra 

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • L. D. Popov
    • 1
  • S. A. Borodkin
    • 1
  • A. A. Tsaturyan
    • 1
  • Yu. P. Tupolova
    • 1
  • S. I. Levchenkov
    • 2
  • V. V. Minin
    • 3
  • A. S. Burlov
    • 4
  • Yu. V. Revinskii
    • 2
  • I. N. Shcherbakov
    • 1
  • E. A. Raspopova
    • 1
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia
  3. 3.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia
  4. 4.Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-on-DonRussia

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