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Influence of ligand donor-acceptor properties on the structure, optical, and electrochemical characteristics of Ir(III) complexes with cyclometallated 2-phenylbenzotiazole

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Abstract

The cis-C,C-structure of a series of cyclometallated Ir(III) complexes with 2-phenylbenzotiazole was determined by the methods of X-ray diffraction (XRD) analysis, 1H, 13C, 31P NMR, and IR spectroscopy. Long-wave absorption bands, phosphorescence, and processes of electrochemical oxidation and reduction of the complexes were assigned to the transfer of electrons presumably located on d π and π* orbitals of cyclometallated 2-phenylbenzotiazole. The decrease in donor and acceptor properties of the ligands leads to the blue shift of absorption spectra and phosphorescence and to the anodic shift of oxidation and reduction potentials of the complexes.

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References

  1. Chi, Y. and Chou, P.T., Chem. Soc. Rev., 2010, vol. 39, no. 3, p. 638. doi 10.1039/B916237B

    Article  CAS  Google Scholar 

  2. Kubas G.J., J. Organomet. Chem., 2009, vol. 694, no. 17, p. 2648. doi 10.1016/j.jorganchem.2009.05.027

    Article  CAS  Google Scholar 

  3. Leung, C.-H., Zhong, H.-J., Chan, D.S-H., and Ma, D.-L., Coord. Chem. Rev., 2013, vol. 257, nos. 11–12, p. 1764. doi 10.1016/j.ccr.2013.01.034

    Article  CAS  Google Scholar 

  4. Zhao, Q, Li, F., and Huang, C., Chem. Soc. Rev., 2010, vol. 39, no. 8, p. 3007. doi 10.1039/B915340C

    Article  CAS  Google Scholar 

  5. Katlenok, E.A., Zolotarev, A.A., and Balashev, K.P., Russ. J. Coord. Chem., 2015, vol. 41, no. 1, p. 37. doi 10.7868/S0132344X15010041

    Article  CAS  Google Scholar 

  6. Katlenok, E.A., Zolotarev, A.A., Ivanov, A.Yu., Smirnov, S.N., Baichurin, R.I., and Balashev, K.P., Russ. J. Gen. Chem., 2015, vol. 85, no. 11, p. 2634. doi 10.1134/S1070363215110213

    Article  CAS  Google Scholar 

  7. Yun, S-J., Song, Y.-K., Kim, M., Shin, J, Jin, S.-H., Kang, S.K., and Kim, Y.-I., Bull. Korean Chem. Soc., 2014, vol. 35, no. 11, p. 3199. doi 10.512/bkcs.2014.35.11.3199

    Article  CAS  Google Scholar 

  8. Radwan, Y.K. Maity, A., and Teets, T.S., Inorg. Chem., 2015, vol. 54, no. 14, p. 1722. doi 10.1021/acs.inorgchem. 5b01401

    Article  Google Scholar 

  9. Fornies, J., Sicilia, V., Casas, J.M., Martin, A., Lopez, J.A., Larraz, C., Borja, P., and Ovejero, C., Dalton Trans., 2011, vol. 40, no. 12, p. 2898. doi 10.1039/C0DT01451F

    Article  CAS  Google Scholar 

  10. Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, New York John Wiley, 1986.

    Google Scholar 

  11. Bonati, F. and Ugo, R., J. Organomet. Chem., 1967, vol. 10, no. 2, p. 257. doi 10.1016/S0022-328X(0000)93085-7

    Article  CAS  Google Scholar 

  12. DeArmond, K., Hanck, K.W., and Wertz, D.W., Coord. Chem. Rev., 1985, vol. 64, p. 65. doi 10.1016/0010-8545(85)-800424

    Article  CAS  Google Scholar 

  13. Katlenok, E.A. and Balashev, K.P., Optics and Spectr., 2013, vol. 114, no. 5, p. 756. doi 10.7868/S0030403413040107

    Article  CAS  Google Scholar 

  14. Lamansky, F., Djurovich, P., Murphy, D., Abdel-Razzaq, F., Le, H.-E., Adachi, C., Burrows, P.E., Forrest, S.R., and Thomson, M.E., J. Am. Chem. Soc., 2001, no. 18, p. 4304. doi 10.1021/ja003693s

    Article  Google Scholar 

  15. Koopmans, T., Phisics, 1933, vol. 1, no. 1, p. 104.

    CAS  Google Scholar 

  16. Sheldrick, G.M., Acta Crystallogr. (A), 2008, vol. 64, no. 1, p. 112. doi 10.1107/S0108767307043930

    Article  CAS  Google Scholar 

  17. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., and Puschmann, H., J. Appl. Crystallogr., 2009, vol. 42, no. 2, p. 339. doi 10.1107/S0021889808042726

    Article  CAS  Google Scholar 

  18. CrysAlisPro, Agilent Technologies, Version 1.171.36.20 (release 6/27/2012)

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Authors and Affiliations

  1. Herzen State Pedagogical University of Russia, nab. reki Moiki 48, St. Petersburg, 191186, Russia

    E. A. Katlenok & K. P. Balashev

  2. St. Petersburg State University, St. Petersburg, Russia

    A. A. Zolotarev

Authors
  1. E. A. Katlenok
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  2. A. A. Zolotarev
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  3. K. P. Balashev
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Corresponding author

Correspondence to K. P. Balashev.

Additional information

Original Russian Text © E.A. Katlenok, A.A. Zolotarev, K.P. Balashev, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 11, pp. 1866–1872.

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Katlenok, E.A., Zolotarev, A.A. & Balashev, K.P. Influence of ligand donor-acceptor properties on the structure, optical, and electrochemical characteristics of Ir(III) complexes with cyclometallated 2-phenylbenzotiazole. Russ J Gen Chem 86, 2508–2514 (2016). https://doi.org/10.1134/S1070363216110177

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  • DOI: https://doi.org/10.1134/S1070363216110177

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