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Functionalized polynorbornenes with fragments of cholic acid and luminophore complexes of iridium(III) and copper(I) in side chains. Synthesis and photophysical properties

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Abstract

Copolymers containing fragments of cholic acid and luminophore complexes of iridium(III) and copper(I) in the side chains have been synthesized by metathesis polymerization. Photophysical properties of the obtained compounds have been investigated. Iridium-containing copolymers demonstrate intense photoluminescence of green, bluish-green and red colors. Copper-containing copolymers generate radiation of green and yellow-green colors. The color of photoluminescence of the metal-containing polymers is determined by the nature of copper(I) and iridium(III) complexes bonded to polymer chain.

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Authors and Affiliations

  1. G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhny Novgorod, 603950, Russia

    E. O. Platonova, A. I. Il’icheva, Yu. P. Parshina, A. V. Rozhkov & L. N. Bochkarev

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  1. E. O. Platonova
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  2. A. I. Il’icheva
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  3. Yu. P. Parshina
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  4. A. V. Rozhkov
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  5. L. N. Bochkarev
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Corresponding author

Correspondence to L. N. Bochkarev.

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Original Russian Text © Е.О. Platonova, А.I. Il’icheva, Yu.P. Parshina, А.V. Rozhkov, L.N. Bochkarev, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 9, pp. 1517–1523.

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Platonova, E.O., Il’icheva, A.I., Parshina, Y.P. et al. Functionalized polynorbornenes with fragments of cholic acid and luminophore complexes of iridium(III) and copper(I) in side chains. Synthesis and photophysical properties. Russ J Gen Chem 86, 2081–2087 (2016). https://doi.org/10.1134/S1070363216090176

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  • DOI: https://doi.org/10.1134/S1070363216090176

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