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Influence of phosphorus concentration on the state of the surface layer of Pd–P hydrogenation catalysts

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Abstract

Phase composition and surface layer state of the Pd–P hydrogenation catalyst formed at various P/Pd ratios from Pd(acac)2 and white phosphorus in a hydrogen atmosphere were determined. Palladium on the catalyst surface is mainly in two chemical states: as Pd(0) clusters and as palladium phosphides. As the P/Pd ratio increases, the fraction and size of palladium clusters decrease, and also the phase composition of formed palladium phosphides changes: Pd3P0.8 → Pd5P2 → PdP2. The causes of the modifying action of phosphorus on the properties of palladium catalysts for hydrogenation of unsaturated compounds were considered.

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Authors and Affiliations

  1. Irkutsk State University, ul. K. Marksa 1, Irkutsk, 664003, Russia

    L. B. Belykh, N. I. Skripov, T. P. Sterenchuk & F. K. Schmidt

  2. A.P. Vinogradov Institute of Geochemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia

    V. V. Akimov & V. L. Tauson

Authors
  1. L. B. Belykh
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  2. N. I. Skripov
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  3. T. P. Sterenchuk
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  4. V. V. Akimov
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  5. V. L. Tauson
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  6. F. K. Schmidt
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Correspondence to L. B. Belykh.

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Original Russian Text © L.B. Belykh, N.I. Skripov, T.P. Sterenсhuk, V.V. Akimov, V.L. Tauson, F.K. Schmidt, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 9, pp. 1454–1465.

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Belykh, L.B., Skripov, N.I., Sterenchuk, T.P. et al. Influence of phosphorus concentration on the state of the surface layer of Pd–P hydrogenation catalysts. Russ J Gen Chem 86, 2022–2032 (2016). https://doi.org/10.1134/S1070363216090073

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  • DOI: https://doi.org/10.1134/S1070363216090073

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