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Synthesis and structure of silver complexes [Ph3(i-Pr)P]+ 2[Ag2I4]2− and [Ph3MeP]+ n[Ag3I4]– n

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Abstract

Complexes [Ph3(i-Pr)P]+ 2[Ag2I4]2- and [Ph3MeP]+ n [Ag3I4]– n were synthesized by the reaction of alkyl (triphenyl)phosphonium iodides with silver iodide in dimethyl sulfoxide. Triphenylalkylphosphonium cations have a tetrahedral configuration. Silver atoms in binuclear anions [Ag2I4]2- are characterized by trigonal coordination, the iodine coordination number being 2 or 1. In the polymeric anions [Ag3I4]– n the silver coordination number is 4 and that of iodine, 2, 3, or 4.

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References

  1. Johnson, L.R. and Davis, B.L., J. Appl. Crystallogr., 1972, vol. 5, p. 194. DOI: 10.1107/S0021889872009197.

    Article  CAS  Google Scholar 

  2. Ansell, G.B., J. Chem. Soc., Perkin Trans. 2, 1976, no. 1, p. 104. DOI: 10.1039/P29760000104.

    Article  Google Scholar 

  3. Geller, S. and Lind, M.D., J. Chem. Phys., 1970, vol. 52, p. 5854. DOI: 10.1063/1.1672869.

    Article  CAS  Google Scholar 

  4. Andersson, S. and Jagner S., Acta Chem. Scand. (A), 1986, vol. 40, p. 52. DOI: 10.3891/acta.chem.scand.40a-0052.

    Article  Google Scholar 

  5. Andersson, S. and Jagner, S., Acta Chem. Scand. (A), 1986, vol. 40, p. 177. DOI: 10.3891/acta.chem. scand.40a-0177.

    Article  Google Scholar 

  6. Andersson, S. and Jagner, S. Acta Chem. Scand. (A), 1988, vol. 42, p. 691. DOI: 10.3891/acta.chem. scand.42a-0691.

    Article  Google Scholar 

  7. Helgesson, G. and Jagner, S., Dalton Trans., 1988, p. 2117. DOI: 10.1039/DT9900002413.

    Google Scholar 

  8. Sharutin, V.V., Senchurin, V.S., Neudachina, A.N., and Somov, N.V., Butlerovsk. Soobshch., vol. 39, no. 8, p. 97.

  9. Bowmaker, G.A., Camus, A., Skelton, B.W., and White, A.H., J. Chem. Soc. Dalton Trans., 1990, no. 3, p. 727. DOI: 10.1039/DT9900000727.

    Article  Google Scholar 

  10. SMART and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the SMART System. Madison (WI, USA): Bruker AXS Inc., 1998.

  11. SHELXTL/PC. Versions 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data. Madison, USA Bruker AXS Inc., 1998.

  12. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., and Puschmann, H., J. Appl. Crystallogr., 2009, vol. 42, p. 339. DOI: 10.1107/S0021889808042726.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. National Southern Ural State Research University, pr. Lenina 76, Chelyabinsk, 454080, Russia

    V. V. Sharutin, O. K. Sharutina, V. S. Senchurin & A. N. Neudachina

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. V. S. Senchurin
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  4. A. N. Neudachina
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Correspondence to V. V. Sharutin.

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Original Russian Text © V.V. Sharutin, O.K. Sharutina, V.S. Senchurin, A.N. Neudachina, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 7, pp. 1177–1182.

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Sharutin, V.V., Sharutina, O.K., Senchurin, V.S. et al. Synthesis and structure of silver complexes [Ph3(i-Pr)P]+ 2[Ag2I4]2− and [Ph3MeP]+ n[Ag3I4]– n . Russ J Gen Chem 86, 1653–1658 (2016). https://doi.org/10.1134/S1070363216070203

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  • DOI: https://doi.org/10.1134/S1070363216070203

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