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Multicomponent cyclothiomethylation of phenylenediamines and 4,4'-diaminodiphenyls with formaldehyde and 1,2-ethanedithiol

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Abstract

One-pot synthesis of bis-1,5,3-dithiazepanes by cyclothiomethylation of o-phenylenediamine, 4,4'-diaminodiphenyl, 4,4'-diaminodiphenyl oxide, and 4,4'-diaminodiphenylmethane with formaldehyde and 1,2- ethanedithiol was performed. Sorption properties of the newly synthesized bis[4-(1,5,3-dithiazepan-3-yl)-phenyl] oxide were investigated by the batch technique. High efficiency of the recovery of palladium(II) with this reagent from hydrochloric acid solutions at room temperature was shown.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Russia

    G. R. Khabibullina, E. S. Fedotova, V. R. Akhmetova & A. G. Ibragimov

  2. Ufa Institute of Chemistry, Russian Academy of Sciences, Ufa, Russia

    G. R. Anpilogova

Authors
  1. G. R. Khabibullina
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  2. E. S. Fedotova
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  3. G. R. Anpilogova
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  4. V. R. Akhmetova
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  5. A. G. Ibragimov
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Correspondence to G. R. Khabibullina.

Additional information

Original Russian Text © G.R. Khabibullina, E.S. Fedotova, G.R. Anpilogova, V.R. Akhmetova, A.G. Ibragimov, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 7, pp. 1130–1134.

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Khabibullina, G.R., Fedotova, E.S., Anpilogova, G.R. et al. Multicomponent cyclothiomethylation of phenylenediamines and 4,4'-diaminodiphenyls with formaldehyde and 1,2-ethanedithiol. Russ J Gen Chem 86, 1608–1612 (2016). https://doi.org/10.1134/S1070363216070124

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  • DOI: https://doi.org/10.1134/S1070363216070124

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