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Promoting non-transition metal alkylation with organic halides in the presence of binary systems based on an organometallic compound and a transition metal compound: IX. Alkylation of aluminum and concluding remarks

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Abstract

Study of aluminum powder alkylation with ethyl bromide in the presence of ethylaluminum sesquibromide and copper(I) iodide has revealed that binary systems based on an organometallic compound and a transition metal compound are efficient promotors of direct synthesis of organoaluminum compounds as well. Major conclusions drawn in a series of studies on non-transition metals (Zn, Cd, and Al) alkylation with organic halides in the presence of the binary systems are summarized.

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Authors and Affiliations

  1. Alekseev Nizhny Novgorod State Technical University, ul. Minina 24, Nizhny Novgorod, 603950, Russia

    I. V. Eremeev

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  1. I. V. Eremeev
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Correspondence to I. V. Eremeev.

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Original Russian Text © I.V. Eremeev, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 7, pp. 1084–1087.

For communication VIII, see [1].

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Eremeev, I.V. Promoting non-transition metal alkylation with organic halides in the presence of binary systems based on an organometallic compound and a transition metal compound: IX. Alkylation of aluminum and concluding remarks. Russ J Gen Chem 86, 1563–1566 (2016). https://doi.org/10.1134/S1070363216070057

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  • DOI: https://doi.org/10.1134/S1070363216070057

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