Abstract
Methods of structuring thermoreversible urethane block copolymers on the basis 3,3-bis-(azidomethyl)oxetane (BAMO) and 3-(azidomethyl)-3-methyloxetane (AMMO) were developed for the first time. Type (AB) n copolymers of BAMO and AMMO have an amorphous crystalline structure but differ from the type B(AB) n copolymers in that they contain less crystal phase and have a higher glass transition temperature and better physicomechanical properties.
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References
Wardle, R.B., Energetic Oxetane Thermoplastic Elastomer Binders, Final Report, Contract no. 00014-90-C-0264, Thiokol, 1994, p. 142.
Kofman, A.S., Petrov, G.N., and Kalaus, A.E., Zh. Vses. Khim. Ova. im. D. I. Mendeleeva, 1974, no. 19, no. 6, p. 676.
Fitken, R.R. and Jeffs, G.M.F., Polymer, 1977, vol. 18, no. 2, p. 197.
Noshay, A. and Mcgrath, J.E., Block Copolymers, New York Academic, 1977.
Miller, Y.A., Lin, S.B., Hwang, K.L.S., et al., Macromolecules, 1985, vol. 18, no 1, pp. 32–34.
Lin, S.B., Hwang, K.S., Jaay, S.Y., and Cooper, S.L., Colloid Polym. Sci., 1985, vol. 2631, no. 1, pp. 128–140.
Kercha, Yu. Yu., Fizicheskaya khimiya poliuretanov (Physical Chemistry of Polyurethanes), Kiev Naukova Dumka, 1979.
Blackwell, Y., Magrjan, M.R., and Hotink, T., Am. Soc. Polym. Prep., 1980, vol. 21, no. 2, p. 303.
Chang, A.L., Briber, R.M., Thomas, E.L., Zdrahala, R.J., and Critchfield, F.E., Polymer, 1982, vol. 23, no. 7, pp. 1060–1068.
Saltykova, N.A., Petrov, A.I., Garaev, I.Kh., and Kostochko, A.V., Zh. SKhST, 1998, no. 52, pp. 64–71.
Saltykova, N.A., Petrov, A.I., Garaev, I.Kh., and Kostochko, A.V., Zh. SKhST, 1998, no. 52, pp. 71–74.
Mikhailov, Yu.M., Badamshina, E.R., Stovbun, E.V., Boepripasy Spetskhim., 2009, no. 2, pp. 54–60.
Bestuzheva, V.V., Dushenok, S.A., Zheltikov, F.A., Kotomin, A.A,, Krauklish, I.V., and Lysov, A.N., Sovr. Problemy Tekh. Khim., 2009, no. 1, pp. 39–44.
Kostochko, A.V., Petrov, A.I., Garaev, I.Kh., and Petrov, V.A., Vest. Kazan. Tekh. Univ., Kazan. 2008.
Kostochko, A.V., Petrov, A.I., and Garaev, I.Kh., Vest. Kazan. Tekh. Univ., Kazan, 2009.
Levichek, M.I., Prosteishie sposoby opytnogo opredeleniya i rascheta kaloriinosti nitroglitserinovykh porokhov (Simplest Methods of Experimental Evaluation and Calculation of the Calorific Efficiency of Nitroglycerin Powders), Levichek, M.I., Ed., Moscow Osoboe Byuro, 1942.
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Original Russian Text © I.Kh. Garaev, A.V. Kostochko, A.I. Petrov, E.N. Ibragimov, A.E. Golubev, 2014, published in Rossiiskii Khimicheskii Zhurnal, 2014, Vol. 58, Nos. 3–4, pp. 32–39.
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Garaev, I.K., Kostochko, A.V., Petrov, A.I. et al. Synthesis of azidourethane block copolymers. Russ J Gen Chem 86, 1469–1475 (2016). https://doi.org/10.1134/S1070363216060396
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DOI: https://doi.org/10.1134/S1070363216060396