Russian Journal of General Chemistry

, Volume 86, Issue 5, pp 1064–1068

Salicylic aldehyde and 2-N-tosylaminobenzaldehyde tetrazolyl hydrazones and their complexes

  • S. I. Levchenkov
  • L. D. Popov
  • I. N. Scherbakov
  • E. A. Raspopova
  • A. N. Morozov
  • A. S. Burlov
  • V. A. Kogan
Article

DOI: 10.1134/S1070363216050133

Cite this article as:
Levchenkov, S.I., Popov, L.D., Scherbakov, I.N. et al. Russ J Gen Chem (2016) 86: 1064. doi:10.1134/S1070363216050133
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Abstract

Tetrazolyl hydrazones of salicylic aldehyde and 2-N-tosylaminobenzaldehyde as well as zinc(II) and copper(II) complexes on their base have been prepared. Quantum-chemical simulation of tautomerism of the hydrazones in vacuum and in the solutions has been performed. IR and NMR spectroscopy and magnetochemistry studies have revealed that the complexes are mononuclear; however, weak intermolecular exchange interaction of the antiferromagnetic type has been detected in the copper(II) complexes.

Keywords

tetrazolyl hydrazone tautomerism Density functional theory coordination compound 

Copyright information

© Pleiades Publishing, Ltd. 2016

Authors and Affiliations

  • S. I. Levchenkov
    • 1
    • 2
  • L. D. Popov
    • 2
  • I. N. Scherbakov
    • 2
  • E. A. Raspopova
    • 2
  • A. N. Morozov
    • 2
  • A. S. Burlov
    • 2
  • V. A. Kogan
    • 2
  1. 1.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia
  2. 2.Southern Federal UniversityRostov-on-DonRussia

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