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Colloid and nanosized catalysts in organic synthesis: XIV. Reductive amination and amidation of carbonitriles catalyzed by nickel nanoparticles

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Abstract

Hydrogenation of carbonitriles catalyzed by nickel nanoparticles in the presence of primary amines led to the predominant formation of unsymmetrical secondary amines. In the presence of secondary amines hydrogenation of nitrites provided enamines as main products. Hydrogenation of nitriles in the presence of formamide or acetamide afforded formyl or acetyl derivatives of primary amines.

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Authors and Affiliations

  1. Volgograd State Technical University, pr. Lenina 28, Volgograd, 400131, Russia

    Yu. V. Popov, V. M. Mokhov & K. V. Shcherbakova

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  1. Yu. V. Popov
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  2. V. M. Mokhov
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  3. K. V. Shcherbakova
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Correspondence to Yu. V. Popov.

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Original Russian Text © Yu.V. Popov, V.M. Mokhov, K.V. Shcherbakova, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 4, pp. 609–616.

For communication XIII, see [1].

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Popov, Y.V., Mokhov, V.M. & Shcherbakova, K.V. Colloid and nanosized catalysts in organic synthesis: XIV. Reductive amination and amidation of carbonitriles catalyzed by nickel nanoparticles. Russ J Gen Chem 86, 798–805 (2016). https://doi.org/10.1134/S107036321604006X

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  • DOI: https://doi.org/10.1134/S107036321604006X

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