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Solubility of d-element salts in organic and aqueous–organic solvents: II. Effect of halocomplex formation on solubility of cobalt bromide and chloride and nickel chloride

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Abstract

Solubility of salts in the systems MCl2–H2O–Solv (M = Co, Ni) and CoBr2–H2O–Solv (Solv = dimethyl sulfoxide, dimethyl formamide, and dimethyl acetamide) at 25°C was measured experimentally. Dominating species of cobalt and nickel halides existing in various concentration regions were identified by analysis of electron absorption spectra. It was shown that the major factor defining solubility is the interaction of halocomplexes of metal ions with solvent molecules.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskaya nab. 7–9, St. Petersburg, 199034, Russia

    A. O. Gorbunov, N. A. Tsyrul’nikov, A. A. Tikhomirova, N. A. Bogachev, M. Yu. Skripkin, A. B. Nikolskii & O. N. Pestova

  2. Department of Chemistry, Center for Photochemical Sciences, Bowling Green State University, Bowling Green, Ohio, USA

    N. A. Tsyrul’nikov & A. A. Tikhomirova

Authors
  1. A. O. Gorbunov
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  2. N. A. Tsyrul’nikov
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  3. A. A. Tikhomirova
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  4. N. A. Bogachev
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  5. M. Yu. Skripkin
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  6. A. B. Nikolskii
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  7. O. N. Pestova
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Corresponding author

Correspondence to M. Yu. Skripkin.

Additional information

Original Russian Text © A.O. Gorbunov, N.A. Tsyrul’nikov, A.A. Tikhomirova, N.A. Bogachev, M.Yu. Skripkin, A.B. Nikolskii, O.N. Pestova, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 4, pp. 581–588.

For communication I, see [1].

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Gorbunov, A.O., Tsyrul’nikov, N.A., Tikhomirova, A.A. et al. Solubility of d-element salts in organic and aqueous–organic solvents: II. Effect of halocomplex formation on solubility of cobalt bromide and chloride and nickel chloride. Russ J Gen Chem 86, 771–777 (2016). https://doi.org/10.1134/S1070363216040022

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  • DOI: https://doi.org/10.1134/S1070363216040022

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