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Spectrophotometric study of dehalogenation of benzyl halides with nickel in aprotic dipolar solvents in the presence of oxygen

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Abstract

Oxidative dissolution of nickel in the benzyl halogenide – dipolar aprotic solvent system in the presence of air oxygen proceeds with the formation of benzaldehyde, benzyl alcohol, 1,2-diphenylethane, and trace amounts of 4,4'-ditolyl. Spectrophotometry studies have revealed that the oxidation products are formed in the solution rather than at the nickel surface. It has been shown that the oxygen adsorbed at the nickel surface practically does not pass into the solution.

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Authors and Affiliations

  1. Tula State University, pr. Lenina 92, Tula, 300600, Russia

    А. М. Egorov & Е. V. Stepanova

  2. FSBI “Tula Interregional Veterinary Laboratory,”, Tula, Russia

    А. N. Novikova

Authors
  1. А. М. Egorov
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  2. А. N. Novikova
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  3. Е. V. Stepanova
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Correspondence to Е. V. Stepanova.

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Original Russian Text © А.М. Egorov, А.N. Novikova, Е.V. Stepanova, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 2, pp. 222–226.

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Egorov, А.М., Novikova, А.N. & Stepanova, Е.V. Spectrophotometric study of dehalogenation of benzyl halides with nickel in aprotic dipolar solvents in the presence of oxygen. Russ J Gen Chem 86, 251–255 (2016). https://doi.org/10.1134/S1070363216020079

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  • DOI: https://doi.org/10.1134/S1070363216020079

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