Skip to main content
SpringerLink
Log in

Salting out of potassium bis(alkylpolyoxyethylene)phosphate with ammonium salts as the base of micellar extraction processes development

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Solubility in the ammonium sulfate (chloride, nitrate)–potassium bis(alkylpolyoxyethylene)-phosphate (oxyphos B)–water pseudo three-component systems has been studied over wide temperature range. The salting-out activity of the ammonium salts towards oxyphos B has been compared, and the possibility of micellar extraction in the studied systems has been demonstrated. Using the ammonium chloride–oxyphos B–water system as an example, extraction of a series of metal ions at 75°С has been performed and compared with the gel-extraction in the ammonium sulfate–oxyphos B–water system at 25°С. It has been found that heating leads to the separation at lower concentration of the components and accelerates the system equilibration.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Yamini, Y. and Ghambarian, M., Comprehensive Sampling and Sample Preparation, London: Elsevier Inc., 2012, vol. 3, p. 657. DOI: 10.1016/B978-0-12- 381373-2.10108-5.

    Article  Google Scholar 

  2. Yazdi, A.S., Trends Anal. Chem., 2011, vol. 30, no. 6, p. 918. DOI: 10.1016/jtrac.2011.02.010.

    Article  CAS  Google Scholar 

  3. Tagashira, S., Ichimaru, T., Nozaki, K., and Murakami, Y., Solvent Extr. Res. Dev. Japan, 2013, vol. 30, p. 39.

    Article  Google Scholar 

  4. Nakai, T., Murakami, Y., Sasaki, Y., and Tagashira, Sh., Talanta, 2005, vol. 66, p. 45. DOI: 10.1016/jtalanta.2004.09.023.

    Article  CAS  Google Scholar 

  5. Kudryashova, O.S., Mokhnatkina, N.N., Lesnov, A.E., and Denisova, S.A., Russ. J. Inorg. Chem., 2010, vol. 55, no. 10, p. 1617. DOI: 10.1134/S0036023610100207.

    Article  CAS  Google Scholar 

  6. Gusev, S.V., Sovremennye problemy nauki i obrazovaniya (Modern Problems of Science and Education), 2012, no. 6. http://science-educationru/106-7988 (appl. date 21.07.2015).

  7. Lesnov, A.E., Kudryashova, O.S., Denisova, S.A., and Cherkasova, A.V., Russ. J. Phys. Chem. (A), 2008, vol. 82, no. 6, p. 1042. DOI: 10.1134/S0036024408060332.

    Article  CAS  Google Scholar 

  8. Kudryashova, O.S., Bortnik, K.A., Chukhlantseva, E.Yu., Denisova, S.A., and Lesnov, A.E., Russ. J. Inorg. Chem., 2013, vol. 58, no. 2, p. 250. DOI: 10.1134/S0036023613020149.

    Article  CAS  Google Scholar 

  9. Ostanina, N.N., Cand. Sci. (Chem.) Dissertation, Saratov, 2013.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Technical Chemistry, Ural Branch, Russian Academy of Sciences, ul. Koroleva 3, Perm, 614013, Russia

    A. M. Elokhov, A. E. Lesnov & O. S. Kudryashova

Authors
  1. A. M. Elokhov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. E. Lesnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. S. Kudryashova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. M. Elokhov.

Additional information

Original Russian Text © A.M. Elokhov, A.E. Lesnov, O.S. Kudryashova, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 11, pp. 1918–1923.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Elokhov, A.M., Lesnov, A.E. & Kudryashova, O.S. Salting out of potassium bis(alkylpolyoxyethylene)phosphate with ammonium salts as the base of micellar extraction processes development. Russ J Gen Chem 85, 2657–2662 (2015). https://doi.org/10.1134/S1070363215110250

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363215110250

Keywords

Search

Navigation