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Synthesis of lanthanide complexes of phthalocyanines containing both naphthoxy and benzotriazole fragments

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Abstract

Interaction of 4-(1-benzotriazolyl)-5-(2-naphthoxy)phthalonitrile with erbium or ytterbium chloride has afforded the lanthanide complexes of tetra-4-(1-benzotriazolyl)tetra-5-(2-naphthoxy)phthalocyanine. Fusion of erbium tetra-4-(1-benzotriazolyl)tetra-5-(2-naphthoxy)phthalocyaninate with phthalonitrile has yielded the corresponding sandwich-type heteroligand complex. The prepared compounds have been characterized by data of elemental analysis as well as IR and electronic spectroscopy; their thermal stability has been studied.

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Authors and Affiliations

  1. Scientific Research Institute of Macroheterocyclic Compounds, Ivanovo State Chemical-Technological University, Sheremetevskii pr. 7, Ivanovo, 153000, Russia

    S. A. Znoiko, O. N. Zubkova, A. V. Borisov, V. E. Maizlish & G. P. Shaposhnikov

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  1. S. A. Znoiko
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  2. O. N. Zubkova
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  3. A. V. Borisov
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  4. V. E. Maizlish
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  5. G. P. Shaposhnikov
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Correspondence to S. A. Znoiko.

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Original Russian Text © S.A. Znoiko, O.N. Zubkova, A.V. Borisov, V.E. Maizlish, G.P. Shaposhnikov, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 11, pp. 1903–1909.

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Znoiko, S.A., Zubkova, O.N., Borisov, A.V. et al. Synthesis of lanthanide complexes of phthalocyanines containing both naphthoxy and benzotriazole fragments. Russ J Gen Chem 85, 2642–2648 (2015). https://doi.org/10.1134/S1070363215110225

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  • DOI: https://doi.org/10.1134/S1070363215110225

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