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Structure, optical, and electrochemical properties of cyclometalated iridium complexes with 2-phenylbenzothiazol, N-(benzothiazole)-N-idoacetamidinate, and N-(thiazole)-N-idoacetamidinate ions

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Abstract

Nucleophilic addition of benzothiazole-2-amine and thiazole-2-amine to acetonitrile bound to iridium in a cyclometalated complex have been discovered. Cis-structure of the iridium complexes with bis{(2-phenyl-3-ido)benzothiazole)[N-(benzothiazole)-N-idoacetamidinate]} and bis{2-phenyl-3-ido)benzothiazole)-[N-(thiazole)-N-idoacetamidinate]} both in crystal and in solution have been proved by X-ray diffraction analysis as well as 1Н, 13С, 15N NMR, and IR spectroscopy.

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Authors and Affiliations

  1. Herzen State Pedagogical University of Russia, nab. reki Moiki 48, St. Petersburg, 191186, Russia

    E. A. Katlenok, A. A. Zolotarev, A. Yu. Ivanov, S. N. Smirnov, R. I. Baichurin & K. P. Balashev

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  1. E. A. Katlenok
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  2. A. A. Zolotarev
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  3. A. Yu. Ivanov
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  4. S. N. Smirnov
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  5. R. I. Baichurin
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  6. K. P. Balashev
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Correspondence to E. A. Katlenok.

Additional information

Original Russian Text © E.A. Katlenok, A.A. Zolotarev, A.Yu. Ivanov, S.N. Smirnov, R.I. Baichurin, K.P. Balashev, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 11, pp. 1896–1902.

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Katlenok, E.A., Zolotarev, A.A., Ivanov, A.Y. et al. Structure, optical, and electrochemical properties of cyclometalated iridium complexes with 2-phenylbenzothiazol, N-(benzothiazole)-N-idoacetamidinate, and N-(thiazole)-N-idoacetamidinate ions. Russ J Gen Chem 85, 2634–2641 (2015). https://doi.org/10.1134/S1070363215110213

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  • DOI: https://doi.org/10.1134/S1070363215110213

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