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Chemical transformations at the silica surface upon sequential interactions with titanium tetrachloride and ammonia vapors

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Abstract

The interaction of titanium oxychloride groups grafted at silica surface with ammonia has been studied considered. The ammonia complexes with titanium atom in an octahedral environment are formed at 20°C. Thermal decomposition of the surface complexes at the temperature range of 20–600°C has been studied, and schemes of the processes occurring under inert and NH3-rich atmospheres have been proposed.

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Authors and Affiliations

  1. St. Petersburg State Institute of Technology, Technical University, Moskovskii pr. 26, St. Petersburg, 190013, Russia

    E. A. Sosnov, A. A. Malkov & A. A. Malygin

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  1. E. A. Sosnov
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  2. A. A. Malkov
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  3. A. A. Malygin
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Correspondence to E. A. Sosnov.

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Original Russian Text © E.A. Sosnov, A.A. Malkov, A.A. Malygin, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 11, pp. 1791–1798.

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Sosnov, E.A., Malkov, A.A. & Malygin, A.A. Chemical transformations at the silica surface upon sequential interactions with titanium tetrachloride and ammonia vapors. Russ J Gen Chem 85, 2533–2540 (2015). https://doi.org/10.1134/S1070363215110067

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  • DOI: https://doi.org/10.1134/S1070363215110067

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