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Physico-chemical study of the complex formation between 2-(tosylamino)benzaldehyde bishydrazones and transition metal ions

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Abstract

New 2-(tosylamino)benzaldehyde bishydrazones and their complexes with copper(II) and zinc(II) have been synthesized. Structure and properties of the prepared compounds have been studied by means of IR and 1H NMR spectroscopy as well as magnetochemistry. Quantum-chemical simulation of the relative stability of tautomeric forms of the bishydrazones has been performed.

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Authors and Affiliations

  1. Southern Federal University, ul. Zorge 7, Rostov-on-Don, 344090, Russia

    L. D. Popov, Yu. P. Tupolova, A. A. Tsaturyan, V. V. Lukov, S. A. Borodkin, I. N. Shcherbakov & I. V. Pankov

  2. Southern Scientific Center of Russian Academy of Sciences, Rostov-on-Don, Russia

    S. I. Levchenkov

  3. Research Institute of Physical and Organic Chemistry of Southern Federal University, Rostov-on-Don, Russia

    A. S. Burlov

  4. North-Caucasian Zonal Research Veterinary Institute, Novocherkassk, Russia

    A. A. Zubenko

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  1. L. D. Popov
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  2. Yu. P. Tupolova
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  3. S. I. Levchenkov
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Correspondence to L. D. Popov.

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Original Russian Text © L.D. Popov, Yu.P. Tupolova, S.I. Levchenkov, A.A. Tsaturyan, V.V. Lukov, S.A. Borodkin, I.N. Shcherbakov, A.S. Burlov, A.A. Zubenko, I.V. Pankov, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 8, pp. 1347–1354.

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Popov, L.D., Tupolova, Y.P., Levchenkov, S.I. et al. Physico-chemical study of the complex formation between 2-(tosylamino)benzaldehyde bishydrazones and transition metal ions. Russ J Gen Chem 85, 1902–1909 (2015). https://doi.org/10.1134/S1070363215080186

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