Russian Journal of General Chemistry

, Volume 85, Issue 8, pp 1902–1909 | Cite as

Physico-chemical study of the complex formation between 2-(tosylamino)benzaldehyde bishydrazones and transition metal ions

  • L. D. Popov
  • Yu. P. Tupolova
  • S. I. Levchenkov
  • A. A. Tsaturyan
  • V. V. Lukov
  • S. A. Borodkin
  • I. N. Shcherbakov
  • A. S. Burlov
  • A. A. Zubenko
  • I. V. Pankov
Article

Abstract

New 2-(tosylamino)benzaldehyde bishydrazones and their complexes with copper(II) and zinc(II) have been synthesized. Structure and properties of the prepared compounds have been studied by means of IR and 1H NMR spectroscopy as well as magnetochemistry. Quantum-chemical simulation of the relative stability of tautomeric forms of the bishydrazones has been performed.

Keywords

bishydrazone quantum-chemical simulation coordination compound magnetochemistry 

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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • L. D. Popov
    • 1
  • Yu. P. Tupolova
    • 1
  • S. I. Levchenkov
    • 2
  • A. A. Tsaturyan
    • 1
  • V. V. Lukov
    • 1
  • S. A. Borodkin
    • 1
  • I. N. Shcherbakov
    • 1
  • A. S. Burlov
    • 3
  • A. A. Zubenko
    • 4
  • I. V. Pankov
    • 1
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Southern Scientific Center of Russian Academy of SciencesRostov-on-DonRussia
  3. 3.Research Institute of Physical and Organic Chemistry of Southern Federal UniversityRostov-on-DonRussia
  4. 4.North-Caucasian Zonal Research Veterinary InstituteNovocherkasskRussia

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