Abstract
Various factors affecting kinetics of acetophenone oxidation with ozone in acetic acid medium at 15–40°C have been examined. Scheme of the acetophenone oxidation with ozone via the radical mechanism has been proposed.
Similar content being viewed by others
References
Galstyan, A.G., Kolbasyuk, O.O., Galstyan, G.A., and Bushuev, A.S., Skhidno-Evrop. Zh. Peredov. Tekhnol., 2013, Vol. 66, No. 6/6, p. 8.
Emanuel’, N.M., Denisov, E.T., and Maizus, Z.K., Tsepnye reaktsii okisleniya uglevodorodov v zhidkoi faze (Liquid-Phase Chain Oxidation of Hydrocarbons), Moscow: Vysshaya Shkola, 1965.
Denisov, E.T., Mitskevich, N.I., and Agabekov, V.E., Mekhanizm zhidkofaznogo okisleniya kislorodsoderzhashchikh soedinenii (The Mechanism of the Liquid-Phase Oxidation of Oxygen-Containing Compounds), Minsk: Nauka i Tekhnika, 1975.
Galstyan, G.A., Tyupalo, N.F., and Razumovskii, S.D., Ozon i ego reaktsii s aromaticheskimi soedineniyami v zhidkoi faze (Ozone and Its Reactions with Aromatic Compounds in the Liquid Phase), Lugansk: Vost.-Ukr. Nats. Univ., 2004.
Bailey, P.S., Ozonation in Organic Chemistry: Olefinic Compounds, New York: Academic, 1978, vol.1.
Razumovs’kii, S.D., Galstyan, G.A., and Tyupalo, M.F., Ozon ta yogo reaktsii z alifatichnimi spolukami (Ozone and Its Reactions with Aliphatic Compounds), Lugans’k: Skhid.-Ukr. Derzhav. Univ., 2000.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.S. Bushuev, A.O. Kolbasyuk, M.A. Lagutenko, G.A. Galstyan, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 8, pp. 1257–1261.
Rights and permissions
About this article
Cite this article
Bushuev, A.S., Kolbasyuk, A.O., Lagutenko, M.A. et al. Kinetics and products of acetophenone oxidation with ozone-air mixture in acetic acid medium. Russ J Gen Chem 85, 1816–1820 (2015). https://doi.org/10.1134/S1070363215080046
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363215080046