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Spectral and theoretical study of 2-methyl-3-{[(Z)-3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methyl]amino}quinazolin-4-one and its complexes with metal ions M(II)

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Abstract

2-Methyl-3-{[(Z)-3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methyl]amino}quinazolin-4-one was synthesized by condensation of 5-hydroxy-4-formyl-3-methyl-1-phenylpyrazole with N-amino-2-methylquinazolin-4-one and its structure and properties were studied by IR, 1H, 13C NMR, 2D 1H NMR (COSY) and electronic spectroscopy and mass-spectrometry. By the reaction of compound (III) with Cd(II), Zn(II), and Pb(II) acetates the intracomplex compounds of 1: 2 composition (metal: ligand) were obtained.

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Correspondence to L. D. Popov.

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Original Russian Text © L.D. Popov, S.A. Borodkin, Yu.P. Tupolova, M.E. Kletskii, O.N. Burov, V.G. Vlasenko, A.S. Burlov, I.N. Shcherbakov, A.A. Zubenko, A.V. Derkun, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 7, pp. 1187–1194.

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Popov, L.D., Borodkin, S.A., Tupolova, Y.P. et al. Spectral and theoretical study of 2-methyl-3-{[(Z)-3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methyl]amino}quinazolin-4-one and its complexes with metal ions M(II). Russ J Gen Chem 85, 1706–1712 (2015). https://doi.org/10.1134/S1070363215070233

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  • DOI: https://doi.org/10.1134/S1070363215070233

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