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Equilibria in ion exchanger-aqueous salt solution systems and clathrate formation

  • Supplement: Rossiiskii Khimicheskii Zhurnal-Zhurnal Rossiiskogo Khimicheskogo Obshchestva im. D.I. Mendeleeva (Russian Chemistry Journal)
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Abstract

The new approach has been developed for the analysis of the data on the equilibria in the systems ionite-aqueous salt solution, based on the application of effective auxiliary functions. With the use of the procedure, that was worked out within the context of the mentioned approach, K+ to Bu4N+ cation-exchange equilibria have been studied between slightly cross-linked sulfonated poly(sterene) cationite Dowex 50Wx2 and three component aqueous solutions of the salts Bu4NBr, KBr. The formation of clathrate-like ion pairs, proposed earlier in the studied system (on the basis of general knowledge on clathrate hydrates), was not revealed in the solution. The suggested approach and procedure can be widely applied to the investigation of all specific cation-anion interactions in aqueous salt solutions.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    V. I. Belevantsev, A. P. Ryzhikh, I. S. Terekhova & G. V. Villeval’d

  2. Novosibirsk State Pedagogical University, Vilyuiskaya ul. 28, Novosibirsk, 630126, Russia

    A. P. Ryzhikh

Authors
  1. V. I. Belevantsev
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  2. A. P. Ryzhikh
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  3. I. S. Terekhova
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  4. G. V. Villeval’d
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Correspondence to V. I. Belevantsev.

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Original Russian Text © V.I. Belevantsev, A.P. Ryzhikh, I.S. Terekhova, G.V. Villeval’d, 2013, published in Rossiiskii Khimicheskii Zhurnal, 2013, Vol. 57, No. 5, pp. 78–85.

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Belevantsev, V.I., Ryzhikh, A.P., Terekhova, I.S. et al. Equilibria in ion exchanger-aqueous salt solution systems and clathrate formation. Russ J Gen Chem 85, 1558–1564 (2015). https://doi.org/10.1134/S1070363215060353

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  • DOI: https://doi.org/10.1134/S1070363215060353

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