Skip to main content
SpringerLink
Log in

Electrical conductivity and interactions in poly(methyl methacrylate)-1-butyl-3-methylimidazolium hexafluorophosphate microheterogeneous system

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Microheterogeneous composite films of varied composition based on poly(methyl methacrylate) and 1-butyl-3-methylimidazoluim hexafluorophosphate have been prepared. The introduction of N-vinylpyrrolidone into the polymer matrix has been shown to deteriorate the electrical conductivity of the composite. Specific ionic conductivity of the composites has been measured as a function of the alternate current frequency and the material composition. Hydrogen bonding between the polymer electrolyte components as well as additional interaction between cation and anion of the ionic liquid encapsulated in the polymer matrix have been confirmed by IR spectroscopy studies.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Dias, F.B., Plomp, L., and Veldhuis, J.B.J., J. Power Sources, 2000, no. 88, p. 169.

    Google Scholar 

  2. Agrawal, R.C. and Pandey, G.P., J. Phys. (D), 2008, vol. 41, p. 223001. DOI: 10.1088/0022-3727/41/22/223001.

    Google Scholar 

  3. Fernicola, A., Scrosati, B., and Ohno, H., Ionics, 2006, vol. 12, p. 95. DOI: 10.1007/s11581-006-0023-5.

    Article  CAS  Google Scholar 

  4. Jiang, J., Gao, D., Li, Z., and Su, G., React. Funct. Polym., 2006, vol. 66, p. 1141. DOI: 10.1016/j.reactfunctpolym.2006.02.004.

    Article  CAS  Google Scholar 

  5. Ramenskaya, L.M. and Grishina, E.P., Russ. J. Phys. Chem. (A), 2009, vol. 83, no. 6, p. 895. DOI: 10.1134/S0036024409060041.

    Article  CAS  Google Scholar 

  6. Ramenskaya, L.M., Grishina, E.P., and Kraeva, O.V., Russ. J. Gen. Chem., 2012, vol. 82, no. 4, p. 749. DOI: 10.1134/S107036321204024X.

    Article  CAS  Google Scholar 

  7. Ye, Y.-S., Rick, J., and Hwang, B.-J., J. Mater. Chem. (A), 2013, vol. 1, p. 2719. DOI: 10.1039/c2ta00126h.

    Article  CAS  Google Scholar 

  8. Grishina, E.P., Ramenskaya, L.M., and Mudrov, A.N., Eur. Polym. J., 2014, vol. 59, p. 247. DOI: 10.1016/j.eurpolymj.2014.073041.

    Article  CAS  Google Scholar 

  9. Gwee, L., Choi, J.-H., Winey, K.I., and Elabd, Y.A., Polymer, 2010, vol. 51, p. 5516. DOI: 10.1016/j.polymer.2010.09.026.

    Article  CAS  Google Scholar 

  10. Hoarfrost, M.L. and Segalman, R.A., Macromolecules, 2011, vol. 44, p. 5281. DOI: org/10.1021/ma200060g.

    Article  CAS  Google Scholar 

  11. Dupont, J., J. Br. Chem. Soc., 2004, vol. 15, no. 3, p. 341.

    Article  CAS  Google Scholar 

  12. Gruzdev, M.S., Ramenskaya, L.M., Chervonova, U.V., and Kumeev, R.S., Russ. J. Gen. Chem., 2009, vol. 79, no. 8, p. 1720. DOI: 10.1134/S1070363209080246.

    Article  CAS  Google Scholar 

  13. Grishina, E.P., Ramenskaya, L.M., Gruzdev, M.S., and Kraeva, O.V., J. Mol. Liq., 2013, vol. 177, p. 247. DOI: 10.1016/j.molliq., 2012.10.23.

    Article  Google Scholar 

  14. Gao, Y., Zhang, L., Wang, Y., and Li, H., J. Phys. Chem. (B), 2010, vol. 114, p. 2828. DOI: 10.1021/jp910528m.

    Article  CAS  Google Scholar 

  15. Chaurasia, S.K., Singh, R.K., and Chandra, S., J. Polym. Sci. (B), 2011, vol. 49, p. 291. DOI: 10.1002/polb.22182.

    Article  CAS  Google Scholar 

  16. Chaurasia, S.K., Singh, R.K., and Chandra, S., Solid State Ionics, 2011, vol. 183, p. 32. DOI: 10.1016/j.ssi.2010.12.008.

    Article  CAS  Google Scholar 

  17. Ramenskaya, L.M., Grishina, E.P., Kraeva, O.V., and Manin, N.G., Russ. J. Gen. Chem., 2012, vol. 82, no. 9, p. 1573. DOI: 10.1134/S1070363212090204.

    Article  CAS  Google Scholar 

  18. O’Reilly, J.M. and Mosher, R.A., Macromolecules, 1981, vol. 14, p. 602.

    Article  Google Scholar 

  19. Ali, A.M.M., Yahya, M.Z.A., Bahron, H., Subban, R.H.Y., Harun, M.K., and Atan, I., Mater. Lett., 2007, vol. 61, p. 2026. DOI: 10.1016/j.matlet.2006.08.008.

    Article  CAS  Google Scholar 

  20. Deepa, M., Sharma, N., and Agnihotry, S.A., J. Mater. Sci., 2002, vol. 37, p. 1759.

    Article  CAS  Google Scholar 

  21. Paulechka, Y.U., Kabo, G.J., Blokhin, A.V., and Vydrov, O.A., Chem. Eng. Data, 2003, vol. 48, p. 457. DOI: 10.1021/je025591i.

    Article  CAS  Google Scholar 

  22. Talaty, E.R., Raja, S., Storhaug, V.J., Do1lle, A., and Carper, W.R., J. Phys. Chem. (B), 2004, vol. 108, p. 13177. DOI: 10.1021/jp040199s.

    Article  CAS  Google Scholar 

  23. Rivera-Rubero, S. and Baldelli, S., J. Phys. Chem. (B), 2006, vol. 110, p. 4756. DOI: 10.1021/jp0563989.

    Article  CAS  Google Scholar 

  24. Dieter, K.M., Dymek, C.J., Jr., Heimer, N.E., Rovang, J.W., and Wilkes, J.S., J. Am. Chem. Soc., 1988, vol. 110, p. 2722.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Krestov Institute of Solutions Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    L. M. Ramenskaya & E. P. Grishina

Authors
  1. L. M. Ramenskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. P. Grishina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. M. Ramenskaya.

Additional information

Original Russian Text © L.M. Ramenskaya, E.P. Grishina, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 6, pp. 1027–1031.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ramenskaya, L.M., Grishina, E.P. Electrical conductivity and interactions in poly(methyl methacrylate)-1-butyl-3-methylimidazolium hexafluorophosphate microheterogeneous system. Russ J Gen Chem 85, 1491–1495 (2015). https://doi.org/10.1134/S1070363215060237

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363215060237

Keywords

Search

Navigation