Abstract
Interaction of polyphenylsiloxane with magnesium acetylacetonate in boiling toluene has been studied. The products isolated via extraction and fractional precipitation have been characterized with elemental analysis, IR spectroscopy, X-ray diffraction analysis, and thermal analysis. The reaction products are polymers containing acetylacetonate group at magnesium atom. Structure of the major product has been suggested.
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Original Russian Text © N.P. Shapkin, A.A. Kapustina, S.V. Gardionov, I.G. Khal’chenko, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 6, pp. 1022–1026.
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Shapkin, N.P., Kapustina, A.A., Gardionov, S.V. et al. Interaction of polyphenylsiloxane with magnesium acetylacetonate. Russ J Gen Chem 85, 1487–1490 (2015). https://doi.org/10.1134/S1070363215060225
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DOI: https://doi.org/10.1134/S1070363215060225