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Kinetic features of N-ethylaniline polymerization

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Abstract

Kinetics of polymerization of N-ethylaniline hydrochloride initiated in aqueous solution by ammonium persulfate has been studied. The auto-catalytic nature of the reaction has been revealed; the order of the catalytic stage has been determined; the rate constants of single-electron transfer and the complex formation have been calculated. Quinonediimine fragments have been found in the poly-N-ethylaniline; their formation mechanism has been suggested.

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Authors and Affiliations

  1. Mendeleev University of Chemical Technology of Russia, Miusskaya pl. 9, Moscow, 125047, Russia

    Ya. O. Mezhuev, Yu. V. Korshak, M. I. Shtilman, S. E. Pokhil & I. S. Strakhov

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  1. Ya. O. Mezhuev
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  2. Yu. V. Korshak
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  3. M. I. Shtilman
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  4. S. E. Pokhil
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  5. I. S. Strakhov
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Correspondence to Ya. O. Mezhuev.

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Original Russian Text © Ya.O. Mezhuev, Yu.V. Korshak, M.I. Shtilman, S.E. Pokhil, I.S. Strakhov, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 6, pp. 1017–1021.

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Mezhuev, Y.O., Korshak, Y.V., Shtilman, M.I. et al. Kinetic features of N-ethylaniline polymerization. Russ J Gen Chem 85, 1482–1486 (2015). https://doi.org/10.1134/S1070363215060213

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  • DOI: https://doi.org/10.1134/S1070363215060213

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