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Functionalization of the double bond in the glycoside of the Stevia rebaudiana plant steviolbioside, as a way to macrocyclic glycosides

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Abstract

The C16=C17 bond in the glycoside steviolbioside from the plant Stevia rebaudiana was oxidized for the first time. Ketone, thiosemicarbazone, and oxime of steviolbioside with a heptaacetylated sophorosyl fragment, as well as binuclear and tetranuclear macrocyclic derivatives of this rebaudioside were synthesized.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088, Russia

    R. R. Sharipova, B. F. Garifullin, O. V. Andreeva, I. Yu. Strobykina, O. B. Bazanova & V. E. Kataev

Authors
  1. R. R. Sharipova
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  2. B. F. Garifullin
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  3. O. V. Andreeva
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  4. I. Yu. Strobykina
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  5. O. B. Bazanova
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  6. V. E. Kataev
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Corresponding author

Correspondence to V. E. Kataev.

Additional information

Original Russian Text © R.R. Sharipova, B.F. Garifullin, O.V. Andreeva, I.Yu. Strobykina, O.B. Bazanova, V.E. Kataev, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 6, pp. 989–999.

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Sharipova, R.R., Garifullin, B.F., Andreeva, O.V. et al. Functionalization of the double bond in the glycoside of the Stevia rebaudiana plant steviolbioside, as a way to macrocyclic glycosides. Russ J Gen Chem 85, 1456–1466 (2015). https://doi.org/10.1134/S107036321506016X

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  • DOI: https://doi.org/10.1134/S107036321506016X

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