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Formation mechanism of nanocrystalline yttrium orthoferrite under heat treatment of the coprecipitated hydroxides

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Abstract

Formation of nanocrystalline yttrium orthoferrite of ∼30 nm average crystallite size from coprecipitated iron(III) and yttrium hydroxides was studied by thermo-X-ray diffractometry and simultaneous thermal analysis over 25–900°C temperature range. A mechanism of physicochemical transformations leading to the formation of YFeO3 nanoparticles was suggested.

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Authors and Affiliations

  1. St. Petersburg State Technological Institute (Technical University), Moskovskii pr. 26, St. Petersburg, 190013, Russia

    V. I. Popkov, O. V. Almjasheva, M. P. Schmidt & V. V. Gusarov

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  1. V. I. Popkov
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  2. O. V. Almjasheva
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  3. M. P. Schmidt
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  4. V. V. Gusarov
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Correspondence to V. I. Popkov.

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Original Russian Text © V.I. Popkov, O.V. Almjasheva, M.P. Schmidt, V.V. Gusarov, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 6, pp. 901–907.

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Popkov, V.I., Almjasheva, O.V., Schmidt, M.P. et al. Formation mechanism of nanocrystalline yttrium orthoferrite under heat treatment of the coprecipitated hydroxides. Russ J Gen Chem 85, 1370–1375 (2015). https://doi.org/10.1134/S107036321506002X

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  • DOI: https://doi.org/10.1134/S107036321506002X

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