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Synthesis, characterization, and antimicrobial activity of complexes of Cu(II), Ni(II), Zn(II), Pb(II), Co(II), Mn(II), and U(VI) containing bidentate Schiff base of [S-methyl-3-(4-methoxybenzylidine)dithiocarbazate]

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Abstract

A novel bidentate Schiff base containing NS donor sequences was synthesized by condensing S-methyldithiocarbazate (SMDTC) with p-anisaldehyde. A series of complexes of the ligand with Cu(II), Ni(II), Zn(II), Pb(II), Co(II), Mn(II) and U(VI) were studied and characterized by various physico-chemical methods. Cu(II), Ni(II) and Zn(II), Pb(II) complexes were four-coordinate with square plannar and tetrahedral geometry respectively. Co(II), Mn(II), and U(VI) complexes were six-coordinate with octahedral geometry. Antimicrobial activity of the prepared complexes was tested as resistance to antimicrobial agents in a wide variety of nosocomial and community-acquired pathogens. The highest antimicrobial activity was detected for the complex Co(II) against candida species.

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Authors and Affiliations

  1. Inorganic Research Laboratory, Department of Chemistry, University of Rajshahi, Rajshahi, 6205, Bangladesh

    Md. Kudrat-E-Zahan & M. S. Islam

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  1. Md. Kudrat-E-Zahan
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  2. M. S. Islam
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Correspondence to Md. Kudrat-E-Zahan.

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Kudrat-E-Zahan, M., Islam, M.S. Synthesis, characterization, and antimicrobial activity of complexes of Cu(II), Ni(II), Zn(II), Pb(II), Co(II), Mn(II), and U(VI) containing bidentate Schiff base of [S-methyl-3-(4-methoxybenzylidine)dithiocarbazate]. Russ J Gen Chem 85, 979–983 (2015). https://doi.org/10.1134/S1070363215040350

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  • DOI: https://doi.org/10.1134/S1070363215040350

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