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Thermochemical study of glycylglycine interaction with polyhydric alcohols in aqueous solution

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Abstract

Integral enthalpies of glycylglycine dissolution (Δsol H m) in aqueous solutions of glycerol, ethylene glycol, and propylene glycol have been determined at the organic co-solvent concentration up to 32 mol %. The standard dissolution enthalpy (Δsol H 0) and standard enthalpy of transfer of the peptide from water into the binary solvent (Δtr H 0) have been calculated. The influence of various types of interactions and the structural features of the interacting molecules on the enthalpy of glycylglycine dissolution has been analyzed.

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Authors and Affiliations

  1. Krestov Institute of Solutions Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    I. N. Mezhevoi & V. G. Badelin

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  1. I. N. Mezhevoi
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  2. V. G. Badelin
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Correspondence to I. N. Mezhevoi.

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Original Russian Text © I.N. Mezhevoi, V.G. Badelin, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 4, pp. 570–574.

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Mezhevoi, I.N., Badelin, V.G. Thermochemical study of glycylglycine interaction with polyhydric alcohols in aqueous solution. Russ J Gen Chem 85, 816–819 (2015). https://doi.org/10.1134/S1070363215040076

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