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N-(R-cyclopropyl)fluorobenzimidoyl phosphonates

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Abstract

Reaction of N-(R-cyclopropyl)benzimidoyl chloride with triethyl phosphite has yielded the corresponding N-(R-cyclopropyl)-substituted benzimidoyl phosphonates existing predominantly in the E-configuration [E : Z ≈ (8–10) : 1] at room temperature. 19F NMR spectroscopy allowed determination of inductive and resonance σ-constants of N-(R-cyclopropyl)-substituted imidoyl chloride and imidoyl phosphonate groups for the first time.

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Authors and Affiliations

  1. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, Kiev, 02094, Ukraine

    P. P. Onys’ko, D. V. Klyukovskii & A. V. Bezdudnyi

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  1. P. P. Onys’ko
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  2. D. V. Klyukovskii
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  3. A. V. Bezdudnyi
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Correspondence to P. P. Onys’ko.

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Original Russian Text © P.P. Onys’ko, D.V. Klyukovskii, A.V. Bezdudnyi, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 2, pp. 245–250.

To the 80th Anniversary of B.I. Ionin

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Onys’ko, P.P., Klyukovskii, D.V. & Bezdudnyi, A.V. N-(R-cyclopropyl)fluorobenzimidoyl phosphonates. Russ J Gen Chem 85, 418–423 (2015). https://doi.org/10.1134/S1070363215020115

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  • DOI: https://doi.org/10.1134/S1070363215020115

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