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Chlorination of secondary phosphine chalcogenides with carbon tetrachloride in the absence of bases

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Abstract

The interaction of bis(2-phenylethyl)phosphine sulfide, bis(2-phenylethyl)phosphine selenide and bis[2-(2-phenyl)propyl]phosphine selenide with carbon tetrachloride under heating (80°C, 8–20 h) leads to the formation of the corresponding chlorophosphine chalcogenides with the yield of 80–90%.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    N. K. Gusarova, P. A. Volkov, N. I. Ivanova, K. O. Khrapova & B. A. Trofimov

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  1. N. K. Gusarova
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  2. P. A. Volkov
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  3. N. I. Ivanova
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  4. K. O. Khrapova
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  5. B. A. Trofimov
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Corresponding author

Correspondence to B. A. Trofimov.

Additional information

Original Russian Text © N.K. Gusarova, P.A. Volkov, N.I. Ivanova, K.O. Khrapova, B.A. Trofimov, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 2, pp. 206–208.

To the 80th Anniversary of B.I. Ionin

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Gusarova, N.K., Volkov, P.A., Ivanova, N.I. et al. Chlorination of secondary phosphine chalcogenides with carbon tetrachloride in the absence of bases. Russ J Gen Chem 85, 380–382 (2015). https://doi.org/10.1134/S107036321502005X

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  • DOI: https://doi.org/10.1134/S107036321502005X

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