Ferrocenoylhydrazone of 2-N-tosylaminobenzaldehyde: Structure, properties, and complexing ability
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- Popov, L.D., Morozov, A.N., Raspopova, E.A. et al. Russ J Gen Chem (2015) 85: 126. doi:10.1134/S1070363215010223
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2-N-Tosylaminobenzaldehyde ferrocenoylhydrazone was synthesized. The crystal structure of the hydrazone was shown to include two independent molecules differing in mutual orientation of the tosyl and ferrocene fragments. Quantum-chemical simulation of the hydrazone tautomerism was performed. Its complexes with Cu(II), Ni(II), Zn(II), and Cd(II) were synthesized and investigated.
Keywordsferrocenoylhydrazones electronic spectroscopy tautomerism X-ray diffraction analysis density functional theory complex formation
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