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Protolytic and complexation properties of the cyclic thiosemicarbazone ligand

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Abstract

The acid-base properties of the thiourea based cyclic thiosemicarbazone have been studied. The tautomerism and complex formation ability of the thiosemicarbazone were investigated by the methods of quantum chemistry and electronic spectroscopy. The complexes of copper(II), nickel(II), cobalt(II), and mercury(II) were synthesized and their structure suggested.

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References

  1. Pandeya, S.N. and Dimmock, J.R., Pharmazie, 1993, vol. 48, no. 9, pp. 659.

    CAS  Google Scholar 

  2. West, D.X., Padhye, S.B., and Sonawane, P.B., Struct. Bond., 1991, vol. 76, pp. 1. DOI: 10.1007/3-540-53499-7_1.

    Article  CAS  Google Scholar 

  3. Bharti, N, Husain, K., Garza, M.T G., Cruz-Vega, D.E., Castro-Garza, J., Mata-Cardenas, B.D., Naqvi, F., and Azam, A., Bioorg. Med. Chem. Lett., 2002, vol. 12, no. 23, pp. 3475. DOI: 10.1016/S0960-894X(02)00703-5.

    Article  CAS  Google Scholar 

  4. Zelenin, K.N., Khorseeva, L.A., and Alekseev, V.V., Pharn. Chem. J., 1992, vol. 26, no. 5, pp. 395.

    Article  Google Scholar 

  5. Dilovic, I., Rubcic, M., Vrdoljak, V., Kraljevic Pavelic, S., Kralj, M., Piantanida, I., and Cindric, M., Bioorg. Med. Chem., 2008, vol. 16, no. 9, pp. 5189. DOI: 10.1016/j.bmc.2008.03.006.

    Article  CAS  Google Scholar 

  6. West, D.X., Liberta, A.E., Padhye, S.B., Chikate, R.C., Sonawane, P.B., Kumbar, A.S., and Yerrende, R.G., Coord. Chem. Rev., 1993, vol. 123, nos. 1–2, pp. 49. DOI: 10.1016/0010-8545(93)85052-6.

    Article  CAS  Google Scholar 

  7. Lobana, T.S., Sharma, R., Bawa, G., and Khanna, S., Coord. Chem. Rev., 2009, vol. 253, nos. 7–8, pp. 977. DOI: 10.1016/j.ccr.2008.07.004.

    Article  CAS  Google Scholar 

  8. Popov, L.D., Morozov, A.N., Shcherbakov, I.N., Tupolova, Yu.P., Lukov, V.V., and Kogan, V.A., Russ. Chem. Rev., 2009, vol. 78, no. 7, pp. 643. DOI: 10.1070/RC2009v078n07ABEH003890.

    Article  CAS  Google Scholar 

  9. Casas, J.S., Garcia-Tasende, M.S., and Sordo, J., Coord. Chem. Rev., 2000, vol., 209, no. 1, pp. 197. DOI: 10.1016/S0010-8545(00)00363-5.

    Article  CAS  Google Scholar 

  10. Soliman, A.A. and Linert, W., Monatch. Chem., 2007, vol. 138, no. 3, pp. 175. DOI: 10.1007/s00706-007-0585-6.

    Article  CAS  Google Scholar 

  11. Ronconi, L. and Sadler, P.J., Coord. Chem. Rev., 2007, vol. 251, nos. 13-14, pp. 1633. DOI: 10.1016/j.ccr.2006.11.017.

    Article  CAS  Google Scholar 

  12. Oliveira, R.B., Souza-Fagundes, E.M., Soares, R.P.P., Andrade, A.A., Krettli, A.U., and Zani, C.L., Eur. J. Med. Chem., 2008, vol. 43, no. 9, pp. 1983. DOI: 10.1016/j.ejmech.2007.11.012.

    Article  Google Scholar 

  13. Smee, D.F. and Sidwell, R.W., Antivir. Res., 2003, vol. 57, nos. 1–2, pp. 41. DOI: 10.1016/S0166-3542(02)00199-7.

    Article  CAS  Google Scholar 

  14. Zeglis, B.M., Divilov, V., and Lewis, J.S., J. Med. Chem., 2011, vol. 54, no. 7, pp. 2391. DOI: 10.1021/jm101532u.

    Article  CAS  Google Scholar 

  15. Rosu, T., Pahontu, E., Pasculescu, S., Georgescu, R., Stanica, N., Curaj, A., Popescu, A., and Leabu, M., Eur. J. Med. Chem., 2010, vol. 45, no. 4, pp. 1627. DOI: 10.1016/j.ejmech.2009.12.015.

    Article  CAS  Google Scholar 

  16. Gazieva, G.A., Polyboyarov, P.A., Popov, L.D., Kolotyrkina, N.G., and Kravchenko, A.N., Synthesis, 2012, vol. 44, no. 21, pp. 3366. DOI: 10.1055/s-0032-1317194.

    Article  CAS  Google Scholar 

  17. Cammi, R., Mennucci, B., and Tomasi, J., J. Phys. Chem. A, 2000, vol. 104, no. 23, pp. 5631. DOI: 10.1021/jp000156l.

    Article  CAS  Google Scholar 

  18. Stephens, P.J., Devlin, F.J., Chabalowski, C.F., and Frisch, M.J., J. Phys. Chem., 1994, vol. 98, no. 45, pp. 11623. DOI: 10.1021/j100096a001.

    Article  CAS  Google Scholar 

  19. Becke, A.D., J. Chem. Phys., 1993, vol. 98, no. 7, pp. 5648. DOI: 10.1063/1.464913.

    Article  CAS  Google Scholar 

  20. Lee, C., Yang, W., and Parr, R.G., Phys. Rev. B, 1988, vol. 37, no. 2, pp. 785. DOI: 10.1103/PhysRevB.37.785.

    Article  CAS  Google Scholar 

  21. Popov, L.D., Mishchenko, A.V., Tupolova, Yu.P., Levchenkov, S.I., Minin, V.V., Ugolkova, E.A., Efimov, N.N., Lukov, V.V., Shcherbakov, I.N., Kogan, V.A., Zubenko, A.A., and Askalepova, O.I., Russ. J. Gen. Chem., 2011, vol. 81, no. 8, pp. 1691. DOI: 10.1134/S107036321108018

    Article  CAS  Google Scholar 

  22. Rakitin, Yu.V. and Kalinnikov, V.T.. Sovremennaya maghetokhimiya (Modern Magnetochemistry), St. Petersburg: Nauka, 1994.

    Google Scholar 

  23. Gaussian 03, Revision D.01. Gaussian, Inc., Wallingford CT, 2004.

  24. Zhurko, G.A. and Zhurko, D.A., Chemcraft ver. 1.6 (build 338). http://www.chemcraftprog.com.

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Authors and Affiliations

  1. Chemical Department, Southern Federal University, Rostov-on-Don, Russia

    L. D. Popov, Yu. N. Tkachenko, O. I. Askalepova, Yu. P. Tupolova & V. A. Kogan

  2. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia

    G. A. Gazieva, A. N. Kravchenko & T. B. Karpova

  3. Southern Scientific Center of the Russian Academy of Sciences, ul. Chekhova 41, Rostov-on-Don, 344022, Russia

    S. I. Levchenkov

Authors
  1. L. D. Popov
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  2. G. A. Gazieva
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  3. A. N. Kravchenko
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  4. Yu. N. Tkachenko
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  5. O. I. Askalepova
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  6. S. I. Levchenkov
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  7. T. B. Karpova
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  8. Yu. P. Tupolova
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  9. V. A. Kogan
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Corresponding author

Correspondence to S. I. Levchenkov.

Additional information

Original Russian Text © L.D. Popov, G.A. Gazieva, A.N. Kravchenko, Yu.N. Tkachenko, O.I. Askalepova, S.I. Levchenkov, T.B. Karpova, Yu.P. Tupolova, V.A. Kogan, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 1, pp. 99–104.

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Popov, L.D., Gazieva, G.A., Kravchenko, A.N. et al. Protolytic and complexation properties of the cyclic thiosemicarbazone ligand. Russ J Gen Chem 85, 92–96 (2015). https://doi.org/10.1134/S1070363215010168

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  • DOI: https://doi.org/10.1134/S1070363215010168

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