Skip to main content
SpringerLink
Log in

Kinetics of reaction between nickel porphyrinates and dicumene peroxide

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Reaction of nickel 5,15-di(o-methoxyphenyl)-2,8,12,18-tetramethyl-3,7,13,17-tetrabutylporphyrinate and 5,10,15,20-tetraphenylporphyrinate with dicumene peroxide in benzene at 295 K was investigated by spectrophotometric method. Kinetic parameters of the reaction were determined, and mechanism of the studied process was suggested. Comparative analysis of the oxidative and reductive properties of nickel porphyrinates in reaction with dicumene peroxide was accomplished. Effect of the electronic and conformation factors on the reaction kinetics was shown. The theoretical calculation of the geometric parameters of the reagents and intermediates of the reaction was performed by PM3 quantum-chemical method.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Koifman, O.I. and Mamardashvili, N.Zh., Ross. Nanotechnol., 2009, vol. 4, nos. 5–6, p. 59.

    Google Scholar 

  2. Koifman, O.I., Ageeva, T.A., and Nikolaeva, O.I., Izv. Vuzov, Ser. Khim. Technol., 2004, vol. 47, no. 5, p. 91.

    CAS  Google Scholar 

  3. Beletskaya, I.P., Tyurin, V.S., Tsivadze, A.Y., Guilard, R., and Stern, C., Chem. Rev., 2009, vol. 109, no. 5, p. 1659. DOI: 10.1021/cr800247a.

    Article  CAS  Google Scholar 

  4. Yashchuk, Yu.P., Tyurin, V.S., and Beletskaya, I.P., Makrogeterotsykly, 2012, vol. 5, nos. 4–5, p. 302.

    CAS  Google Scholar 

  5. Milaeva, E.R., Gerasimova, O.A., Jingwei, Zhangt, Shpakovsky, D.B., Syrbu, S.A., Semeykin, A.S., Koifman, O.I., Kireeva, E.G., Shevtsova, E.F., Bachurin, S.J., and Zefirov, N.S., J. Inorg. Biochem., 2008, vol. 102, p. 1348. DOI: 10.1016/j.jinorgbio.2008.01.022.

    Article  CAS  Google Scholar 

  6. Lomova, T.N., Motorina, E.V., Ovchenkova, E.N., and Klyueva, M.E., Russ. Chem. Bull., 2007, vol. 56, no. 4, p. 660. DOI: 10.1007/s11172-007-0105-1.

    Article  CAS  Google Scholar 

  7. Afanasiev, P., Millet, J.-M.M., Bouchu, D., Kudrik, E.V., and Sorokin A.B., Dalton Trans., 2011, vol. 40, p. 701. DOI: 10.1039/C0DT00958J.

    Article  CAS  Google Scholar 

  8. Afanasiev, P., Bouchu, D., Kudrik, E.V., Millet, J.-M.M., and Sorokin A.B., Dalton Trans., 2009, p. 9828.

    Google Scholar 

  9. Zaitseva, S.V., Zdanovich, S.A., and Koifman, O.I., Russ. J. Gen. Chem., 2005, vol. 75, no. 5, p. 800. DOI: 1007/s11176-005-0321-z.

    Article  CAS  Google Scholar 

  10. Simonova, O.R., Zaitseva, S.V., and Koifman, O.I., Russ. J. Gen. Chem., 2008, vol. 78, no. 6, p. 1260. DOI: 10.1134/S1070363208060285.

    Article  CAS  Google Scholar 

  11. Simonova, O.R., Zaitseva, S.V., and Koifman, O.I., Russ. J. Coord. Chem., 2009, vol. 35, no. 5, p. 320. DOI: 10.1134/S1070328409050029.

    Article  CAS  Google Scholar 

  12. Lomova, T.N., Tyulyaeva, E.Y., and Klyueva, M.E., Russ. J. Phys. Chem. (A), 2011, vol. 85, no. 6, p. 926. DOI: 10.1134/S0036024411060215.

    Article  CAS  Google Scholar 

  13. Bichan, N.G., Tyulyaeva, E.Yu. and Lomova, T.N., Makrogeterotsykly, 2013, vol. 6, no. 2, p. 144.

    CAS  Google Scholar 

  14. Thies, S., Bornholdt, C., Kohler, F., Sonnichsen, F.D., Nather, C., Tuczek, F., and Herges, R., Chem. Eur. J., 2010, vol. 16, p. 10074.

    Article  CAS  Google Scholar 

  15. Cheremenskaya, O.V., Solov’eva, A.B., Ponomarev, G.V., and Timashev, S.F., Russ. J. Phys. Chem. (A), 2001, vol. 75, no. 10, p. 1633.

    Google Scholar 

  16. Zaitseva, S.V., Zdanovich, S.A., and Golubchikov, O.A., Russ. J. Coord. Chem., 2002, vol. 28, no. 12, p. 843.

    Article  CAS  Google Scholar 

  17. Simonova, O.R., Zaitseva, S.V., and Koifman, O.I., Russ. J. Gen. Chem., 2013, vol. 83, no. 1, p. 110. DOI: 10.1134/S1070363213010192.

    Article  CAS  Google Scholar 

  18. Schidt, M.W., Baldridge, K.K., Boatz, J.A., Elbert, S.T., Gordon, M.S., Jensen, J.H., Koseki, S., Matsunaga, N., Nguyen, K.A., Su, S., Windus, T.L., Dupuis, M., and Montgomeri, J.A., J. Comput. Chem., 1993, vol. 14, no. 11, p. 1347. DOI: 10.1002/jcc.540141112.

    Article  Google Scholar 

  19. Stewart, J.J.P., J. Computer-Aided Mol. Design, 1990, vol. 4, p. 1. DOI: 10.1007/BF00128336.

    Article  Google Scholar 

  20. Fletcher, R. Methods of Optimization. New York: John Wiley & Sons, 1980.

    Google Scholar 

  21. Eksperimental’nye metody khimicheskoi kinetiki (Experimental Methods of Chemical Kinetis), Emanuel’, N.M. and Sergeev, G.B., Eds., Moscow: Vysshaya Shkola, 1980.

    Google Scholar 

  22. Lindsey, J.S. and Woodford, J.N., Inorg. Chem., 1995, no. 34, p. 1063. DOI: 1021/ic00109a011.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    O. P. Simonova, S. V. Zaitseva & O. I. Koifman

  2. Ivanovo State Chemical and Technological University, Ivanovo, Russia

    O. I. Koifman

Authors
  1. O. P. Simonova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. V. Zaitseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. I. Koifman
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to O. P. Simonova.

Additional information

Original Russian Text © O.P. Simonova, S.V. Zaitseva, O.I. Koifman, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 12, pp. 2012–2019.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Simonova, O.P., Zaitseva, S.V. & Koifman, O.I. Kinetics of reaction between nickel porphyrinates and dicumene peroxide. Russ J Gen Chem 84, 2429–2435 (2014). https://doi.org/10.1134/S1070363214120135

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363214120135

Keywords

Search

Navigation