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Effect of mechanical activation on kinetic features of BaZrO3 formation

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Abstract

Barium zirconate BaZrO3 has been prepared via heating of equimolar mixture of BaCO3 with ZrO2 at 900–1050°C with and without preliminary mechanical activation of the reactants. Degree of BaZrO3 formation has been analyzed using basic equations of kinetics of solid-phase reactions in comparison with analogous synthesis of strontium and calcium zirconates. The relative efficiency of mechanical activation in the zirconates synthesis follows the Ca > Sr ≈ Ba series.

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Authors and Affiliations

  1. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Science Center, Russian Academy of Sciences, Akademgorodok 26a, Apatity, 184209, Russia

    A. M. Kalinkin, K. V. Balyakin & E. V. Kalinkina

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  1. A. M. Kalinkin
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  2. K. V. Balyakin
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  3. E. V. Kalinkina
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Correspondence to A. M. Kalinkin.

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Original Russian Text © A.M. Kalinkin, K.V. Balyakin, E.V. Kalinkina, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 12, pp. 1969–1974.

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Kalinkin, A.M., Balyakin, K.V. & Kalinkina, E.V. Effect of mechanical activation on kinetic features of BaZrO3 formation. Russ J Gen Chem 84, 2388–2392 (2014). https://doi.org/10.1134/S1070363214120056

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  • DOI: https://doi.org/10.1134/S1070363214120056

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