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Preparation and luminescent properties of coordination polymers of terbium and europium with 1,4-bis-(4-methoxycarbonyl-3-hydroxyphenoxycarbonyl)butane

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Abstract

Physicochemical properties of new isostructural homo- and heteronuclear coordination polymers of terbium and europium with 1,4-bis-(4-methoxycarbonyl-3-hydroxyphenoxycarbonyl)butane (H2L) differing in the composition have been studied. The Tb2L3·H2O compound has exhibited efficient sensibilized green luminescence, whereas the corresponding europium-containing polymer EuL3·H2O has shown practically no luminescence due to mismatch of energies of the ligand triplet level and the Eu3+ ion emitting level. Heteronuclear terbium-europium polymers (Tb1.5Eu0.5L3·H2O, TbEuL3·H2O, and Tb0.5Eu1.5L3·H2O) show luminescence via the intramolecular transfer of the exiting energy from Tb3+ emitting level to Eu3+.

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Authors and Affiliations

  1. Bogatski Physicochemical Institute, National Academy of Science of Ukraine, Lyustdorfskaya dor. 86, Odessa, 65080, Ukraine

    I. I. Zseltvay, S. B. Meshkova, N. S. Novikova, R. V. Kondrat’eva, V. I. Nedostup, P. G. Doga, Yu. V. Skripinets & E. A. Zhikhareva

Authors
  1. I. I. Zseltvay
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  2. S. B. Meshkova
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  3. N. S. Novikova
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  4. R. V. Kondrat’eva
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  5. V. I. Nedostup
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  6. P. G. Doga
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  7. Yu. V. Skripinets
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  8. E. A. Zhikhareva
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Correspondence to I. I. Zseltvay.

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Original Russian Text © I.I. Zseltvay, S.B. Meshkova, N.S. Novikova, R.V. Kondrat’eva, V.I. Nedostup, P.G. Doga, Yu.V. Skripinets, E.A. Zhikhareva, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 10, pp. 1717–1724.

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Zseltvay, I.I., Meshkova, S.B., Novikova, N.S. et al. Preparation and luminescent properties of coordination polymers of terbium and europium with 1,4-bis-(4-methoxycarbonyl-3-hydroxyphenoxycarbonyl)butane. Russ J Gen Chem 84, 1994–2000 (2014). https://doi.org/10.1134/S1070363214100223

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  • DOI: https://doi.org/10.1134/S1070363214100223

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