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Binuclear complexes of copper(II) with 1′-phthalazinylhydrazones of substituted salicylic aldehydes: Physico-chemical study and quantum-chemical simulation

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Abstract

Binuclear complexes of copper(II) with 1′-phthalazinylhydrazones of substituted salicylic aldehydes have been prepared and studied. Antiferromagnetic exchange interaction between copper(II) ions has been revealed in all the complexes. Taking advantage of quantum-chemical simulation, we have investigated the influence of the complexes structural isomerism on the character of the exchange interaction between the paramagnetic centers. X-ray absorbance spectroscopy afforded the structural parameters of coordination spheres of copper(II) ions; it has been demonstrated that dimerization occurred via the nitrogen atoms of phthalazine fragments.

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Authors and Affiliations

  1. Southern Scientific Center, Russian Academy of Sciences, ul. Chekhova 41, Rostov-on-Don, 344006, Russia

    S. I. Levchenkov

  2. Southern Federal University, Rostov-on-Don, Russia

    L. D. Popov, I. N. Shcherbakov, V. G. Vlasenko, A. A. Tsaturyan, S. S. Beloborodov, A. M. Ionov & V. A. Kogan

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  1. S. I. Levchenkov
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  2. L. D. Popov
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  3. I. N. Shcherbakov
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Correspondence to S. I. Levchenkov.

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Original Russian Text © S.I. Levchenkov, L.D. Popov, I.N. Shcherbakov, V.G. Vlasenko, A.A. Tsaturyan, S.S. Beloborodov, A.M. Ionov, V.A. Kogan, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 10, pp. 1693–1701.

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Levchenkov, S.I., Popov, L.D., Shcherbakov, I.N. et al. Binuclear complexes of copper(II) with 1′-phthalazinylhydrazones of substituted salicylic aldehydes: Physico-chemical study and quantum-chemical simulation. Russ J Gen Chem 84, 1970–1978 (2014). https://doi.org/10.1134/S1070363214100193

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