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Synthesis, X-ray structure, and stevens rearrangement of 1,1-di(prop-2-yn-1-yl)-2,5-dihydro-1H-pyrrol-1-ium bromide

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Abstract

1,1-Di(prop-2-yn-1-yl)-2,5-dihydro-1H-Pyrrol-1-ium bromide was obtained with interaction of 3-pyrroline with propargyl bromide and its structure was studied by X-ray analysis. It has been shown that the Stevens rearrangement of obtaining salt leads to the formation of 1-(hexa-4,5-dien-1-yn-3-yl)-2,5-dihydro-1H-pyrrol.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Scientific and Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of Armenia, 26 Azatutyan ave., Yerevan, 0014, Armenia

    A. Kh. Gyul’nazaryan, T. A. Sahakyan, G. T. Sargsyan, J. V. Grigoryan, A. G. Aivazyan & R. A. Tamanyan

Authors
  1. A. Kh. Gyul’nazaryan
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  2. T. A. Sahakyan
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  3. G. T. Sargsyan
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  4. J. V. Grigoryan
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  5. A. G. Aivazyan
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  6. R. A. Tamanyan
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Corresponding author

Correspondence to A. Kh. Gyul’nazaryan.

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Original Russian Text © A.Kh. Gyul’nazaryan, T.A. Sahakyan, G.T. Sargsyan, J.V. Grigoryan, A.G. Aivazyan, R.A. Tamanyan, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 10, pp. 1660–1662.

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Gyul’nazaryan, A.K., Sahakyan, T.A., Sargsyan, G.T. et al. Synthesis, X-ray structure, and stevens rearrangement of 1,1-di(prop-2-yn-1-yl)-2,5-dihydro-1H-pyrrol-1-ium bromide. Russ J Gen Chem 84, 1938–1940 (2014). https://doi.org/10.1134/S1070363214100132

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  • DOI: https://doi.org/10.1134/S1070363214100132

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