Skip to main content
SpringerLink
Log in

Promoting alkylation of non-transition metals with organic halides in the presence of binary systems based on organometallic compound and transition metal compound: II. Comparative study of efficiency of various agents in the course of destruction of passivating film on the surface of alkylated metal

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

It has been demonstrated that alkylzinc halides efficiently destroy the passivating film on the zinc-copper pair in the course of its alkylation with ethyl bromide to give ethylzinc bromide. The alkylzinc halides efficiency is comparable to that of ethyl iodide and exceeds that of salts of transition or non-transition metals as well as of ultraviolet irradiation. Addition of alkylzinc halides or metal salts as well as ultraviolet irradiation have practically no effect on the developed reaction. The results have demonstrated that the organometallic component of the binary systems is polyfunctional; this permits a generalization of known features of a number of known methods promoting direct synthesis of organometallic compounds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Eremeev, I.V., Russ. J. Gen. Chem., 2014, vol. 84, no. 8, p. 1561. DOI: 10.1134/S1070363214080222.

    Article  CAS  Google Scholar 

  2. Dankov, P.D., Ignatov, D.V., and Shishakov, N.A., Elektronograficheskie issledovaniya okisnykh i gidro-okisnykh plenok na metallakh (Electron Diffraction Studies of Oxide and Hydroxide Films on Metals), Moscow: Akad. Nauk SSSR, 1953.

    Google Scholar 

  3. Kubaschewsci, O. and Hopkins, B.E., Oxidation of Metals and Alloys, 2nd ed., London: Butterworths, 1962.

    Google Scholar 

  4. Evdokimov, V.D. and Semov, Yu.I., Ekzoelektronnaya emissiya pri trenii (Exoelectronic Emission in Friction), Moscow: Nauka, 1973.

    Google Scholar 

  5. Akimov, A.G. and Rozenfel’d, I.L., Russ. Chem. Rev., 1974, vol. 43, no. 4, p. 251.

    Article  Google Scholar 

  6. Karyakin, Yu.V. and Angelov, I.I., Chistye khimicheskie veshchestva (Pure Chemical Substances), Moscow: Khimiya, 1974.

    Google Scholar 

  7. Handbook of Chemistry and Physics, Lide, D.R., Ed., Boca Raton: Taylor&Francis, 2007.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nizhni Novgorod State Technical University, ul. Minina 24, Nizhni Novgorod, 603950, Russia

    I. V. Eremeev

Authors
  1. I. V. Eremeev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. V. Eremeev.

Additional information

Original Russian Text © I.V. Eremeev, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 10, pp. 1629–1635.

For communication I, see [1].

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Eremeev, I.V. Promoting alkylation of non-transition metals with organic halides in the presence of binary systems based on organometallic compound and transition metal compound: II. Comparative study of efficiency of various agents in the course of destruction of passivating film on the surface of alkylated metal. Russ J Gen Chem 84, 1909–1914 (2014). https://doi.org/10.1134/S1070363214100077

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363214100077

Keywords

Search

Navigation