Skip to main content
SpringerLink
Log in

Photocatalytic activity and intercalation of layered perovskite-like tantalates ANdTa2O7 (A = H, Li, Na, K, Rb, Cs)

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Layered perovskite-like oxides ANdTa2O7 (A = H, Li, Na, K, Rb, Cs) were synthesized and characterized by means of diffuse reflection spectroscopy, thermogravimetry, and simultaneous thermal and X-ray phase analysis. Comparative analysis of the photocatalytic activity of ANdTa2O7 in the UV-induced hydrogen evolution from an aqueous isopropanol solution was performed. NaNdTa2O7 and HNdTa2O7 are able to intercalate water to the interlayer space. The compositions and thermal stability ranges of intercalates were determined. No explicit correlation between the photocatalytic activity of layered oxides and their ability to intercalate water to the interlayer space was found.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Sivakumar, T. and Gopalakrishnan, J., Mater. Res. Bull., 2005, vol. 40, no. 1, p. 39. DOI: 10.1016/j.materresbull.2004.09.015.

    Article  CAS  Google Scholar 

  2. Shimizu, K., Tsuji, Y., Hatamachi, T., Toda, K., Kodama, T., Sato, M., and Kitayama, Y., Phys. Chem., 2004, vol. 6, p. 1064. DOI: 10.1039/b312620j.

    CAS  Google Scholar 

  3. Huang, Y., Li, J., Wei, Y., Li, Y., Lin, J., and Wu, J., J. Hazard. Mater., 2009, vol. 166, no. 1, p. 103. DOI: 10.1016/j.jhazmat.2008. 11.040.

    Article  CAS  Google Scholar 

  4. Huang, Y., Wei, Y., Fan, L., Huang, M., Lin, J., and Wu, J., Int. J. Hydrogen Energ., 2009, vol. 34, no. 13, p. 5318. DOI: 10.1016/j.ijhydene.2009.04.040.

    Article  CAS  Google Scholar 

  5. Rodionov, I.A., Silyukov, O.I., and Zvereva, I.A., Russ. J. Gen. Chem., 2012, vol. 82, no. 4, p. 635. DOI: 10.1134/S1070363212040032.

    Article  CAS  Google Scholar 

  6. Rodionov, I.A., Silyukov, O.I., Utkina, T.D., Chislov, M.V., Sokolova, Y.P., and Zvereva, I.A., Russ. J. Gen. Chem., 2012, vol. 82, no. 7, p. 1191. DOI: 10.1134/S1070363212070018.

    Article  CAS  Google Scholar 

  7. Huang, Y., Li, Y., Wei, Y., Huang, M., and Wu, J., Sol. Energy Mater. Sol. Cells, 2011, vol. 95, no. 3, p. 1019. DOI: 10.1016/j.solmat.2010.12.017.

    Article  CAS  Google Scholar 

  8. Machida, M., Miyazaki, K., Matsushima, S., and Arai, M., J. Mater. Chem., 2003, vol. 13, no. 6, p. 1433. DOI: 10.1039/B301938C.

    Article  CAS  Google Scholar 

  9. Wu, J., Yibin, L., Huang, Y., Huang, M., and Lin, J., J. Hazard. Mater., 2010, vol. 177, p. 458. DOI: 10.1016/j.jhazmat.2009. 12.005.

    Article  Google Scholar 

  10. Silyukov, O., Chislov, M., Burovikhina, A., Utkina, T., and Zvereva, I., J. Therm. Anal. Calorim., 2012, vol. 110, p. 187. DOI: 10.1007/s10973-012-2198-5.

    Article  CAS  Google Scholar 

  11. Dion, M., Ganne, M., and De Chimie, L., Mater. Res. Bull., 1981, vol. 16, no. 11, p. 1429. DOI: 0025-5408/81/111429-07$02.00/0.

    Article  CAS  Google Scholar 

  12. Hermann, A.T. and Wiley, J.B., Mater. Res. Bull., 2009, vol. 44, no. 5, p. 1046. DOI: 10.1016/j.materresbull.2008.10.019.

    Article  CAS  Google Scholar 

  13. Mitsuyama, T., Tsutsumi, A., Sato, S., Ikeue, K., and Machida, M., J. Solid State Chem., 2008, vol. 181, p. 1419. DOI: 10.1016/j.jssc.2008.03.020.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    A. A. Burovikhina, M. V. Chislov, I. A. Rodionov, D. A. Porotnikov & I. A. Zvereva

Authors
  1. A. A. Burovikhina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. V. Chislov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. A. Rodionov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. D. A. Porotnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. A. Zvereva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. A. Zvereva.

Additional information

Original Russian Text © A.A. Burovikhina, M.V. Chislov, I.A. Rodionov, D.A. Porotnikov, I.A. Zvereva, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 10, pp. 1612–1617.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Burovikhina, A.A., Chislov, M.V., Rodionov, I.A. et al. Photocatalytic activity and intercalation of layered perovskite-like tantalates ANdTa2O7 (A = H, Li, Na, K, Rb, Cs). Russ J Gen Chem 84, 1893–1898 (2014). https://doi.org/10.1134/S1070363214100041

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363214100041

Keywords

Search

Navigation