Skip to main content
SpringerLink
Log in

Distribution of dopant metals between PbTiO3 crystals and PbO-B2O3 flux

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Single crystals of lead titanate PbTiO3 doped with silicon, calcium, chromium, manganese, cobalt, nickel, copper, zinc, and cadmium were grown. The compositions and crystallographic parameters of the crystals were studied. The lowest distribution coefficients of dopants between PbTiO3 crystals and flux were observed with Mn+2 and Co+2 and the highest, with Ca+2. Doping with niobium leads to the formation of solid solutions with the pyrochlore structure A2B2O7 and even higher distribution coefficient. A correlation was found between dopant concentrations and crystal cell parameters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Lv, H., Gao, H., Yang, Y., and Liu, L., Appl. Catal. A, 2011, vol. 404, p. 54. DOI: 10.1016/j.apcata.2011.07.010.

    CAS  Google Scholar 

  2. Chebanova, E.V., Kabiri, Y., Kupriyanov, M.F., Vasil, T.M., and Pustovaya, L.E., Fazovyie perekhody, uporyado-chennye sostoianya i novye materialy (Phase Transitions Ordered States and New Materials), Rostov-on-Don: Rostov. Gos. Univ., 2007, vol. 7, p. 1.

    Google Scholar 

  3. Zhang, S. and Li, F., J. Appl. Phys., 2012, vol. 111, p. 031301. DOI: 10.1063/1.3679521.

    Article  Google Scholar 

  4. Park, S.E. and Shrout, T.R., J. Appl. Phys., 1997, vol. 82, p. 1804. DOI: 10.1063/1.365983.

    Article  CAS  Google Scholar 

  5. Fu, H. and Cohen, R.E., Nature, 2000, vol. 403, p. 281. DOI: 10.1038/35002022.

    Article  CAS  Google Scholar 

  6. Davis, M., J. Electroceram., 2007, vol. 19, p. 23. DOI: 10.1007/s10832-007-9046-1.

    Article  CAS  Google Scholar 

  7. Zhang, S.J., Lebrun, L., Randall, C.A., and Shrout, T.R., J. Crystal Growth, 2004, vol. 267, p. 204. DOI: 1016/j.jcrysgro. 2004.03.063.

    Article  CAS  Google Scholar 

  8. Priya, S., Kim, H.W., Ryu, J.H., Zhang, S.J., Shrout, T.R., and Uchino, K., J. Appl. Phys., 2002, vol. 92, p. 3923. DOI: 10.1063/1.1503411.

    Article  CAS  Google Scholar 

  9. Zhang, S.J., Lee, M., Kim, D.H., Lee, H.Y., and Shrout, T.R., Appl. Phys. Lett., 2008, vol. 93, p. 122908. DOI: 10.1063/1.2992081.

    Article  Google Scholar 

  10. Shrelock, N.P., Zhang, S.J., Luo, J., Lee, H.Y., Shrout, T.R., and Meyer, R.J., J. Appl. Phys., 2010, vol. 107, p. 074108. DOI: 10.1063/1.3359716.

    Article  Google Scholar 

  11. Tamashpolsky, J.J., Venevtsev, Y., and Zhdanov, G.S., Crystallography, 1968, vol. 13, p. 521.

    Google Scholar 

  12. Bachelier, J., Hervieu, M., and Quemeneur, E., Bull. Soc. Chim. Fr., 1973, p. 2593.

    Google Scholar 

  13. Shannon, R.D., Acta Crystallogr., 1976, vol. 32, p. 751. DOI: 10.1107/S0567739476001551.

    Article  Google Scholar 

  14. Nelmes, R.J. and Kuhs, W.F., Solid State Commun., 1985, vol. 54, p. 721. DOI: 10.1016/0038-1098(85) 90595-2.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. South Ural State University, pr. Lenina 76, Chelyabinsk, 454080, Russia

    D. A. Vinnik, D. A. Zherebtsov & G. G. Mikhailov

  2. Institute of Inorganic Chemistry, University of Stuttgart, Stuttgart, Germany

    R. Niewa

  3. Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    L. I. Isaenko

  4. Novosibirsk State University, Novosibirsk, Russia

    L. I. Isaenko

Authors
  1. D. A. Vinnik
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. A. Zherebtsov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. Niewa
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. I. Isaenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. G. Mikhailov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to D. A. Vinnik.

Additional information

Original Russian Text © D.A. Vinnik, D.A. Zherebtsov, R. Niewa, L.I. Isaenko, G.G. Mikhailov, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 10, pp. 1607–1611.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Vinnik, D.A., Zherebtsov, D.A., Niewa, R. et al. Distribution of dopant metals between PbTiO3 crystals and PbO-B2O3 flux. Russ J Gen Chem 84, 1888–1892 (2014). https://doi.org/10.1134/S107036321410003X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107036321410003X

Keywords

Search

Navigation