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Structure of aqueous electrolyte solutions estimated by near infrared spectroscopy and chemometric analysis of spectral data

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Abstract

The IR spectra of aqueous solutions of MClO4, MNO3, MCl (M = Li, Na), CsCl, and Na2SO4 were measured at frequencies of 5400–7500 cm−1 over a wide concentration range from 0.12 M up to saturation concentrations at 25°C. Chemometric analysis of the experimental data matrix was performed. Regularity was detected in distribution of the IR spectra of the studied aqueous solutions on the the plot of analysis scores by the principal component method depending on the nature of the anion-water interaction. The influence of the nature of the salt anion and cation on the water structure in aqueous electrolyte solutions was demonstrated. The existence and interconversion of the spectral forms of water with changing electrolyte concentration in solution were revealed.

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References

  1. Frank, H.S. and Wen, W.-Y., Disc. Faraday Soc., 1957, vol. 24, p. 133.

    Article  Google Scholar 

  2. Lilich, L.S. and Khripun, M.K., Rastvory kak khimicheskie sistemy. Donorno-aktseptornye reaktsii v rastvorakh (Solutions as Chemical Systems: Donor-Acceptor Reactions in Solutions), St. Petersburg: Sankt-Peterb. Gos. Univ., 2010.

    Google Scholar 

  3. Stewart, G.H., Ind. J. Phys., 1932, vol. 7, no. 5, p. 603.

    Google Scholar 

  4. Davidian, A.G, Pestova, O.N., Starova, G.L., Gurzhii, V.V., Myund, L.A., and Khripun, M.K., Russ. J. Gen. Chem., 2012, vol. 82, no. 4, p. 621. DOI: 10.1134/S1070363212040019.

    Article  CAS  Google Scholar 

  5. Neilson, G.W. and Enderby, J.E., Proc. R. Soc. London, Ser. A, 1983, vol. 390, no. 1799, p. 353.

    Article  CAS  Google Scholar 

  6. Hertz, H.G. and Mazitov, R., Ber. Bunsen. Phys. Chem., 1981, vol. 85, no. 12, p. 1103.

    Article  CAS  Google Scholar 

  7. Samoilov, O.Ya., Struktura vodnykh rastvorov elektrolitov i gidratatsiya ionov (The Structure of Aqueous Solutions of Electrolytes and Ion Hydration), Moscow: Akad. Nauk SSSR, 1957.

    Google Scholar 

  8. Kirgintsev, A.N., Trushnikova, L.N., and Lavrent’eva, V.G., Rastvorimost’ neorganicheskikh veshchestv v vode (Solubility of Inorganic Substances in Water), Leningrad: Khimiya, 1972.

    Google Scholar 

  9. Kudrev, A.G., Koord. Khim., 1999, vol. 25, no. 2, p. 152.

    Google Scholar 

  10. Kudrev, A.G., Zh. Neorg. Khim., 2001, vol. 46, no. 5, p. 854

    CAS  Google Scholar 

  11. Kudrev, A.G., Polym. Sci., Ser. A, 2000, vol. 42, p. 527.

    Google Scholar 

  12. Gargallo, R., Eritja, R., and Kudrev, A.G., Russ. J. Gen. Chem., 2010, vol. 80, no. 3, p. 485. DOI: 10.1134/S1070363210030205.

    Article  CAS  Google Scholar 

  13. Bucek, P., Gargallo, R., and Kudrev, A.G., Anal. Chim. Acta, 2010, vol. 683, p. 69. DOI: 10.1016/j.aca.2010.10.008.

    Article  CAS  Google Scholar 

  14. Davidian, A.G., Kudrev, A.G., Myund, L.A., and Khripun, M.K., Russ. J. Gen. Chem., 2013, vol. 83, no. 3, p. 415. DOI: 10.1134/S107036321303002X.

    Article  Google Scholar 

  15. Subramanian, S. and Fisher, H.F., J. Chem. Phys., 1972, vol. 76, no. 1, p. 84. DOI: 10.1021/j100645a015.

    Article  CAS  Google Scholar 

  16. Chen, Y., Zhang, Y.H., and Zhao, L.J., Phys. Chem. Chem. Phys., 2004, vol. 6, p. 537. DOI: 10.1039/b311768e.

    Article  CAS  Google Scholar 

  17. Gowen, A.A., Amigo, J.M., and Tsenkova, R., Anal. Chim. Acta, 2013, vol. 759, p. 8. DOI: 10.1016/j.aca.2012.10.007.

    Article  CAS  Google Scholar 

  18. Max, J.J., De Blois, S., Veilleux, A., and Chapados, C., Can. J. Chem., 2001, vol. 79, p. 13. DOI: 10.1139/cjc-79-1-13.

    Article  CAS  Google Scholar 

  19. Max, J.J. and Chapados, C., J. Chem. Phys., 2000, vol. 113, no. 16, p. 6803. DOI: 10.1063/1.1290133.

    Article  CAS  Google Scholar 

  20. Max, J.J. and Chapados, C., J. Chem. Phys., 2001, vol. 115, no. 6, p. 2664. DOI: 10.1063/1.1337047.

    Article  CAS  Google Scholar 

  21. James, D.W. and Armishaw, R.F., Aust. J. Chem., 1975, vol. 28, p. 1179.

    Article  CAS  Google Scholar 

  22. Chomnilpan, S., Liminga, R., and Tellgren, R., Acta Crystallogr., Sect. B, 1977, vol. 33, p. 3954. DOI: 10.1107/S0567740877012588.

    Article  Google Scholar 

  23. Hermansson, K., Thomas, J.O., and Olovsson, I., Acta Crystallogr., Sect. B, 1977, vol. 33, p. 2857.

    Article  Google Scholar 

  24. Berglund, B., Tomas, J.O., and Tellgren, R., Acta Crystallogr., Sect. B, 1975, vol. 31, p. 1842. DOI: 10.1107/S0567740875006346.

    Article  Google Scholar 

  25. Lerner, H.W. and Bolte, M., Acta Crystallogr., Sect. E, 2003, vol. 53, p. 20.

    Article  Google Scholar 

  26. Klewe, B. and Pedersen, B., Acta Crystallogr., Sect. B, 1974, vol. 30, p. 2363.

    Article  Google Scholar 

  27. Kristiansson, O., Acta Univ. Upsaliensis, 1989, p. 1.

    Google Scholar 

  28. Smith, D.W., J. Chem. Educ., 1977, vol. 54, no. 9, p. 540. DOI: 10.1021/ed054p540.

    Article  CAS  Google Scholar 

  29. Latysheva, V.A., Vestn. Sankt-Petersb. Gos. Univ., Ser. 4, 1998, issue 4 (no. 25), p. 99.

    Google Scholar 

  30. Davidian, A.G., Kudrev, A.G., Myund, L.A., and Khripun M.K., J. Near Infrared Spectr., 2014, vol. 22, p. 27. DOI: 10.1255/jnirs.1090.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    A. G. Davidian, A. G. Kudrev, L. A. Myund, O. S. Khlynova & M. K. Khripun

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  1. A. G. Davidian
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  2. A. G. Kudrev
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  3. L. A. Myund
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  4. O. S. Khlynova
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  5. M. K. Khripun
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Correspondence to A. G. Davidian.

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Original Russian Text © A.G. Davidian, A.G. Kudrev, L.A. Myund, O.S. Khlynova, M.K. Khripun, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 10, pp. 1596–1606.

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Davidian, A.G., Kudrev, A.G., Myund, L.A. et al. Structure of aqueous electrolyte solutions estimated by near infrared spectroscopy and chemometric analysis of spectral data. Russ J Gen Chem 84, 1877–1887 (2014). https://doi.org/10.1134/S1070363214100028

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  • DOI: https://doi.org/10.1134/S1070363214100028

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