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Comparative analysis of structural parameters of the nearest surrounding of nitrate and perchlorate ions in aqueous solutions of electrolytes

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Abstract

Data on structural parameters of the nearest surrounding of nitrate and perchlorate ions in aqueous solutions under standard conditions have been generalized. Hydration numbers, interparticle distances, and ionic association types have been discussed and compared. The major difference between the ions is that nitrate ion tends to form ion pairs, whereas perchlorate ion does not.

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  1. Krestov Institute of Solutions Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    P. R. Smirnov

  2. Ivanovo State University of Chemistry and Technology, Ivanovo, Russia

    P. R. Smirnov

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Original Russian Text © P.R. Smirnov, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 10, pp. 1585–1595.

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Smirnov, P.R. Comparative analysis of structural parameters of the nearest surrounding of nitrate and perchlorate ions in aqueous solutions of electrolytes. Russ J Gen Chem 84, 1867–1876 (2014). https://doi.org/10.1134/S1070363214100016

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